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(E)-Methyl N′-(2-hydroxy-3-methoxybenzylidene)hydrazinecarboxylate
The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The non-H atoms of the molecule are essentially coplanar, with a maximum deviation of 0.015 (2) Å. An intramolecular O—H⋯N interaction is observed. In the crystal structure, the molecules ar...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969457/ https://www.ncbi.nlm.nih.gov/pubmed/21582834 http://dx.doi.org/10.1107/S1600536809021631 |
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author | Lv, Lu-Ping Yu, Wen-Bo Li, Wei-Wei Zhang, Yong-Zhao Hu, Xian-Chao |
author_facet | Lv, Lu-Ping Yu, Wen-Bo Li, Wei-Wei Zhang, Yong-Zhao Hu, Xian-Chao |
author_sort | Lv, Lu-Ping |
collection | PubMed |
description | The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The non-H atoms of the molecule are essentially coplanar, with a maximum deviation of 0.015 (2) Å. An intramolecular O—H⋯N interaction is observed. In the crystal structure, the molecules are linked into a two-dimensional network parallel to the ac plane by N—H⋯O hydrogen bonds involving the methoxy O atom and by two C—H⋯O hydrogen bonds involving the carbonyl O atom. In addition, an intermolecular C—H⋯π interaction is observed. |
format | Text |
id | pubmed-2969457 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29694572010-12-30 (E)-Methyl N′-(2-hydroxy-3-methoxybenzylidene)hydrazinecarboxylate Lv, Lu-Ping Yu, Wen-Bo Li, Wei-Wei Zhang, Yong-Zhao Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The non-H atoms of the molecule are essentially coplanar, with a maximum deviation of 0.015 (2) Å. An intramolecular O—H⋯N interaction is observed. In the crystal structure, the molecules are linked into a two-dimensional network parallel to the ac plane by N—H⋯O hydrogen bonds involving the methoxy O atom and by two C—H⋯O hydrogen bonds involving the carbonyl O atom. In addition, an intermolecular C—H⋯π interaction is observed. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969457/ /pubmed/21582834 http://dx.doi.org/10.1107/S1600536809021631 Text en © Lv et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Lv, Lu-Ping Yu, Wen-Bo Li, Wei-Wei Zhang, Yong-Zhao Hu, Xian-Chao (E)-Methyl N′-(2-hydroxy-3-methoxybenzylidene)hydrazinecarboxylate |
title | (E)-Methyl N′-(2-hydroxy-3-methoxybenzylidene)hydrazinecarboxylate |
title_full | (E)-Methyl N′-(2-hydroxy-3-methoxybenzylidene)hydrazinecarboxylate |
title_fullStr | (E)-Methyl N′-(2-hydroxy-3-methoxybenzylidene)hydrazinecarboxylate |
title_full_unstemmed | (E)-Methyl N′-(2-hydroxy-3-methoxybenzylidene)hydrazinecarboxylate |
title_short | (E)-Methyl N′-(2-hydroxy-3-methoxybenzylidene)hydrazinecarboxylate |
title_sort | (e)-methyl n′-(2-hydroxy-3-methoxybenzylidene)hydrazinecarboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969457/ https://www.ncbi.nlm.nih.gov/pubmed/21582834 http://dx.doi.org/10.1107/S1600536809021631 |
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