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(E)-Methyl N′-(2-hydr­oxy-3-methoxy­benzyl­idene)hydrazinecarboxyl­ate

The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The non-H atoms of the mol­ecule are essentially coplanar, with a maximum deviation of 0.015 (2) Å. An intra­molecular O—H⋯N inter­action is observed. In the crystal structure, the mol­ecules ar...

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Detalles Bibliográficos
Autores principales: Lv, Lu-Ping, Yu, Wen-Bo, Li, Wei-Wei, Zhang, Yong-Zhao, Hu, Xian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969457/
https://www.ncbi.nlm.nih.gov/pubmed/21582834
http://dx.doi.org/10.1107/S1600536809021631
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author Lv, Lu-Ping
Yu, Wen-Bo
Li, Wei-Wei
Zhang, Yong-Zhao
Hu, Xian-Chao
author_facet Lv, Lu-Ping
Yu, Wen-Bo
Li, Wei-Wei
Zhang, Yong-Zhao
Hu, Xian-Chao
author_sort Lv, Lu-Ping
collection PubMed
description The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The non-H atoms of the mol­ecule are essentially coplanar, with a maximum deviation of 0.015 (2) Å. An intra­molecular O—H⋯N inter­action is observed. In the crystal structure, the mol­ecules are linked into a two-dimensional network parallel to the ac plane by N—H⋯O hydrogen bonds involving the meth­oxy O atom and by two C—H⋯O hydrogen bonds involving the carbonyl O atom. In addition, an intermolecular C—H⋯π inter­action is observed.
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spelling pubmed-29694572010-12-30 (E)-Methyl N′-(2-hydr­oxy-3-methoxy­benzyl­idene)hydrazinecarboxyl­ate Lv, Lu-Ping Yu, Wen-Bo Li, Wei-Wei Zhang, Yong-Zhao Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The non-H atoms of the mol­ecule are essentially coplanar, with a maximum deviation of 0.015 (2) Å. An intra­molecular O—H⋯N inter­action is observed. In the crystal structure, the mol­ecules are linked into a two-dimensional network parallel to the ac plane by N—H⋯O hydrogen bonds involving the meth­oxy O atom and by two C—H⋯O hydrogen bonds involving the carbonyl O atom. In addition, an intermolecular C—H⋯π inter­action is observed. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969457/ /pubmed/21582834 http://dx.doi.org/10.1107/S1600536809021631 Text en © Lv et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lv, Lu-Ping
Yu, Wen-Bo
Li, Wei-Wei
Zhang, Yong-Zhao
Hu, Xian-Chao
(E)-Methyl N′-(2-hydr­oxy-3-methoxy­benzyl­idene)hydrazinecarboxyl­ate
title (E)-Methyl N′-(2-hydr­oxy-3-methoxy­benzyl­idene)hydrazinecarboxyl­ate
title_full (E)-Methyl N′-(2-hydr­oxy-3-methoxy­benzyl­idene)hydrazinecarboxyl­ate
title_fullStr (E)-Methyl N′-(2-hydr­oxy-3-methoxy­benzyl­idene)hydrazinecarboxyl­ate
title_full_unstemmed (E)-Methyl N′-(2-hydr­oxy-3-methoxy­benzyl­idene)hydrazinecarboxyl­ate
title_short (E)-Methyl N′-(2-hydr­oxy-3-methoxy­benzyl­idene)hydrazinecarboxyl­ate
title_sort (e)-methyl n′-(2-hydr­oxy-3-methoxy­benzyl­idene)hydrazinecarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969457/
https://www.ncbi.nlm.nih.gov/pubmed/21582834
http://dx.doi.org/10.1107/S1600536809021631
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