N-(2-Methyl­phen­yl)-6-(1H-pyrazol-1-yl)pyridazin-3-amine

The title compound, C(14)H(13)N(5), crystallizes with two crystallographically independent mol­ecules in the unit cell. The two mol­ecules form dimers through inter­molecular N—H⋯N and C—H⋯N hydrogen bonds. The hydrogen-bonding motifs are R (2) (2)(8) for both the N—H⋯N and C—H⋯N inter­actions. The...

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Detalles Bibliográficos
Autores principales: Ather, Abdul Qayyum, Tahir, M. Nawaz, Khan, Misbahul Ain, Athar, Muhammad Makshoof
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969459/
https://www.ncbi.nlm.nih.gov/pubmed/21582895
http://dx.doi.org/10.1107/S1600536809022867
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author Ather, Abdul Qayyum
Tahir, M. Nawaz
Khan, Misbahul Ain
Athar, Muhammad Makshoof
author_facet Ather, Abdul Qayyum
Tahir, M. Nawaz
Khan, Misbahul Ain
Athar, Muhammad Makshoof
author_sort Ather, Abdul Qayyum
collection PubMed
description The title compound, C(14)H(13)N(5), crystallizes with two crystallographically independent mol­ecules in the unit cell. The two mol­ecules form dimers through inter­molecular N—H⋯N and C—H⋯N hydrogen bonds. The hydrogen-bonding motifs are R (2) (2)(8) for both the N—H⋯N and C—H⋯N inter­actions. The pyrazole and pyrimidine rings form dihedral angles of 6.2 (3) and 8.3 (3)° with each other and the dihedral angles between the pyrazole and benzene rings are 54.9 (2) and 58.6 (2)°. The benzene rings of neighbouring dimers also exhibit C—H⋯π inter­actions.
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spelling pubmed-29694592010-12-30 N-(2-Methyl­phen­yl)-6-(1H-pyrazol-1-yl)pyridazin-3-amine Ather, Abdul Qayyum Tahir, M. Nawaz Khan, Misbahul Ain Athar, Muhammad Makshoof Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(13)N(5), crystallizes with two crystallographically independent mol­ecules in the unit cell. The two mol­ecules form dimers through inter­molecular N—H⋯N and C—H⋯N hydrogen bonds. The hydrogen-bonding motifs are R (2) (2)(8) for both the N—H⋯N and C—H⋯N inter­actions. The pyrazole and pyrimidine rings form dihedral angles of 6.2 (3) and 8.3 (3)° with each other and the dihedral angles between the pyrazole and benzene rings are 54.9 (2) and 58.6 (2)°. The benzene rings of neighbouring dimers also exhibit C—H⋯π inter­actions. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969459/ /pubmed/21582895 http://dx.doi.org/10.1107/S1600536809022867 Text en © Ather et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ather, Abdul Qayyum
Tahir, M. Nawaz
Khan, Misbahul Ain
Athar, Muhammad Makshoof
N-(2-Methyl­phen­yl)-6-(1H-pyrazol-1-yl)pyridazin-3-amine
title N-(2-Methyl­phen­yl)-6-(1H-pyrazol-1-yl)pyridazin-3-amine
title_full N-(2-Methyl­phen­yl)-6-(1H-pyrazol-1-yl)pyridazin-3-amine
title_fullStr N-(2-Methyl­phen­yl)-6-(1H-pyrazol-1-yl)pyridazin-3-amine
title_full_unstemmed N-(2-Methyl­phen­yl)-6-(1H-pyrazol-1-yl)pyridazin-3-amine
title_short N-(2-Methyl­phen­yl)-6-(1H-pyrazol-1-yl)pyridazin-3-amine
title_sort n-(2-methyl­phen­yl)-6-(1h-pyrazol-1-yl)pyridazin-3-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969459/
https://www.ncbi.nlm.nih.gov/pubmed/21582895
http://dx.doi.org/10.1107/S1600536809022867
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AT atharmuhammadmakshoof n2methylphenyl61hpyrazol1ylpyridazin3amine

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