Tetra­aqua­bis(4,4′-bipyridine)zinc(II) bis­(trans-4-hydroxy­cinnamate)

The title complex, [Zn(C(10)H(8)N(2))(2)(H(2)O)(4)](C(9)H(7)O(3))(2), was obtained by the hydro­thermal reaction of zinc sulfate with mixed 4-hydroxy­lcinnamic acid (H(2) L) and 4,4′-bipyridine (4,4′-bipy) ligands. The complex consists of a centrosymmetric [Zn(4,4′-bipy)(2)(H(2)O)(4)](2+) cation wit...

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Detalles Bibliográficos
Autor principal: Chen, Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969468/
https://www.ncbi.nlm.nih.gov/pubmed/21582731
http://dx.doi.org/10.1107/S1600536809023204
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author Chen, Ling
author_facet Chen, Ling
author_sort Chen, Ling
collection PubMed
description The title complex, [Zn(C(10)H(8)N(2))(2)(H(2)O)(4)](C(9)H(7)O(3))(2), was obtained by the hydro­thermal reaction of zinc sulfate with mixed 4-hydroxy­lcinnamic acid (H(2) L) and 4,4′-bipyridine (4,4′-bipy) ligands. The complex consists of a centrosymmetric [Zn(4,4′-bipy)(2)(H(2)O)(4)](2+) cation with the metal centre in a distorted ZnN(2)O(4) coordination, and of two HL (−) anions. Extensive O—H⋯O and O—H⋯N hydrogen-bonding inter­actions between the constituents lead to the formation of a three-dimensional network.
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spelling pubmed-29694682010-12-30 Tetra­aqua­bis(4,4′-bipyridine)zinc(II) bis­(trans-4-hydroxy­cinnamate) Chen, Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Zn(C(10)H(8)N(2))(2)(H(2)O)(4)](C(9)H(7)O(3))(2), was obtained by the hydro­thermal reaction of zinc sulfate with mixed 4-hydroxy­lcinnamic acid (H(2) L) and 4,4′-bipyridine (4,4′-bipy) ligands. The complex consists of a centrosymmetric [Zn(4,4′-bipy)(2)(H(2)O)(4)](2+) cation with the metal centre in a distorted ZnN(2)O(4) coordination, and of two HL (−) anions. Extensive O—H⋯O and O—H⋯N hydrogen-bonding inter­actions between the constituents lead to the formation of a three-dimensional network. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969468/ /pubmed/21582731 http://dx.doi.org/10.1107/S1600536809023204 Text en © Ling Chen 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Ling
Tetra­aqua­bis(4,4′-bipyridine)zinc(II) bis­(trans-4-hydroxy­cinnamate)
title Tetra­aqua­bis(4,4′-bipyridine)zinc(II) bis­(trans-4-hydroxy­cinnamate)
title_full Tetra­aqua­bis(4,4′-bipyridine)zinc(II) bis­(trans-4-hydroxy­cinnamate)
title_fullStr Tetra­aqua­bis(4,4′-bipyridine)zinc(II) bis­(trans-4-hydroxy­cinnamate)
title_full_unstemmed Tetra­aqua­bis(4,4′-bipyridine)zinc(II) bis­(trans-4-hydroxy­cinnamate)
title_short Tetra­aqua­bis(4,4′-bipyridine)zinc(II) bis­(trans-4-hydroxy­cinnamate)
title_sort tetra­aqua­bis(4,4′-bipyridine)zinc(ii) bis­(trans-4-hydroxy­cinnamate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969468/
https://www.ncbi.nlm.nih.gov/pubmed/21582731
http://dx.doi.org/10.1107/S1600536809023204
work_keys_str_mv AT chenling tetraaquabis44bipyridinezinciibistrans4hydroxycinnamate

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