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Poly[diethylenetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]]
In the title compound, {(C(4)H(16)N(3))[La(SO(4))(3)(H(2)O)]}(n), the La atom adopts an irregular LaO(9) coordination geometry, including one bonded water molecule. The three sulfate groups adopt both monodentate and bidentate coordination to the metal ions. Two of the sulfate groups serve as bridg...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969472/ https://www.ncbi.nlm.nih.gov/pubmed/21582717 http://dx.doi.org/10.1107/S1600536809022272 |
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author | Wang, Yuan-Rui Hu, Yong-Sheng Shi, Cui-Li Li, Dan-Ping Li, Ya-Feng |
author_facet | Wang, Yuan-Rui Hu, Yong-Sheng Shi, Cui-Li Li, Dan-Ping Li, Ya-Feng |
author_sort | Wang, Yuan-Rui |
collection | PubMed |
description | In the title compound, {(C(4)H(16)N(3))[La(SO(4))(3)(H(2)O)]}(n), the La atom adopts an irregular LaO(9) coordination geometry, including one bonded water molecule. The three sulfate groups adopt both monodentate and bidentate coordination to the metal ions. Two of the sulfate groups serve as bridges in the (100) and (010) directions, yielding infinite sheets, whereas the third is pendant to one La(3+) cation. The protonated organic species interacts with the layers by way of N—H⋯O hydrogen bonds, and O–H⋯O hydrogen bonds involving aqua ligands also occur. |
format | Text |
id | pubmed-2969472 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29694722010-12-30 Poly[diethylenetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]] Wang, Yuan-Rui Hu, Yong-Sheng Shi, Cui-Li Li, Dan-Ping Li, Ya-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {(C(4)H(16)N(3))[La(SO(4))(3)(H(2)O)]}(n), the La atom adopts an irregular LaO(9) coordination geometry, including one bonded water molecule. The three sulfate groups adopt both monodentate and bidentate coordination to the metal ions. Two of the sulfate groups serve as bridges in the (100) and (010) directions, yielding infinite sheets, whereas the third is pendant to one La(3+) cation. The protonated organic species interacts with the layers by way of N—H⋯O hydrogen bonds, and O–H⋯O hydrogen bonds involving aqua ligands also occur. International Union of Crystallography 2009-06-17 /pmc/articles/PMC2969472/ /pubmed/21582717 http://dx.doi.org/10.1107/S1600536809022272 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Yuan-Rui Hu, Yong-Sheng Shi, Cui-Li Li, Dan-Ping Li, Ya-Feng Poly[diethylenetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]] |
title | Poly[diethylenetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]] |
title_full | Poly[diethylenetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]] |
title_fullStr | Poly[diethylenetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]] |
title_full_unstemmed | Poly[diethylenetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]] |
title_short | Poly[diethylenetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]] |
title_sort | poly[diethylenetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(iii)]] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969472/ https://www.ncbi.nlm.nih.gov/pubmed/21582717 http://dx.doi.org/10.1107/S1600536809022272 |
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