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Poly[diethyl­enetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]]

In the title compound, {(C(4)H(16)N(3))[La(SO(4))(3)(H(2)O)]}(n), the La atom adopts an irregular LaO(9) coordination geometry, including one bonded water mol­ecule. The three sulfate groups adopt both monodentate and bidentate coordination to the metal ions. Two of the sulfate groups serve as bridg...

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Autores principales: Wang, Yuan-Rui, Hu, Yong-Sheng, Shi, Cui-Li, Li, Dan-Ping, Li, Ya-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969472/
https://www.ncbi.nlm.nih.gov/pubmed/21582717
http://dx.doi.org/10.1107/S1600536809022272
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author Wang, Yuan-Rui
Hu, Yong-Sheng
Shi, Cui-Li
Li, Dan-Ping
Li, Ya-Feng
author_facet Wang, Yuan-Rui
Hu, Yong-Sheng
Shi, Cui-Li
Li, Dan-Ping
Li, Ya-Feng
author_sort Wang, Yuan-Rui
collection PubMed
description In the title compound, {(C(4)H(16)N(3))[La(SO(4))(3)(H(2)O)]}(n), the La atom adopts an irregular LaO(9) coordination geometry, including one bonded water mol­ecule. The three sulfate groups adopt both monodentate and bidentate coordination to the metal ions. Two of the sulfate groups serve as bridges in the (100) and (010) directions, yielding infinite sheets, whereas the third is pendant to one La(3+) cation. The protonated organic species inter­acts with the layers by way of N—H⋯O hydrogen bonds, and O–H⋯O hydrogen bonds involving aqua ligands also occur.
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spelling pubmed-29694722010-12-30 Poly[diethyl­enetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]] Wang, Yuan-Rui Hu, Yong-Sheng Shi, Cui-Li Li, Dan-Ping Li, Ya-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {(C(4)H(16)N(3))[La(SO(4))(3)(H(2)O)]}(n), the La atom adopts an irregular LaO(9) coordination geometry, including one bonded water mol­ecule. The three sulfate groups adopt both monodentate and bidentate coordination to the metal ions. Two of the sulfate groups serve as bridges in the (100) and (010) directions, yielding infinite sheets, whereas the third is pendant to one La(3+) cation. The protonated organic species inter­acts with the layers by way of N—H⋯O hydrogen bonds, and O–H⋯O hydrogen bonds involving aqua ligands also occur. International Union of Crystallography 2009-06-17 /pmc/articles/PMC2969472/ /pubmed/21582717 http://dx.doi.org/10.1107/S1600536809022272 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yuan-Rui
Hu, Yong-Sheng
Shi, Cui-Li
Li, Dan-Ping
Li, Ya-Feng
Poly[diethyl­enetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]]
title Poly[diethyl­enetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]]
title_full Poly[diethyl­enetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]]
title_fullStr Poly[diethyl­enetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]]
title_full_unstemmed Poly[diethyl­enetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]]
title_short Poly[diethyl­enetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]]
title_sort poly[diethyl­enetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(iii)]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969472/
https://www.ncbi.nlm.nih.gov/pubmed/21582717
http://dx.doi.org/10.1107/S1600536809022272
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