Chloridobis(ethyl­enediamine-κ(2) N,N′)(n-pentyl­amine-κN)cobalt(III) dichloride monhydrate

The title complex, [CoCl(C(5)H(13)N)(C(2)H(8)N(2))(2)]Cl(2)·H(2)O, comprises one chloridobis(ethyl­enediamine)(n-pentyl­amine)cobalt(III) cation, two chloride counter-anions and a water mol­ecule. The Co(III) atom of the complex is hexa­coordinated by five N and one Cl atoms. The five N atoms are fr...

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Detalles Bibliográficos
Autores principales: Anbalagan, K., Tamilselvan, M., Nirmala, S., Sudha, L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969482/
https://www.ncbi.nlm.nih.gov/pubmed/21582753
http://dx.doi.org/10.1107/S1600536809022764
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author Anbalagan, K.
Tamilselvan, M.
Nirmala, S.
Sudha, L.
author_facet Anbalagan, K.
Tamilselvan, M.
Nirmala, S.
Sudha, L.
author_sort Anbalagan, K.
collection PubMed
description The title complex, [CoCl(C(5)H(13)N)(C(2)H(8)N(2))(2)]Cl(2)·H(2)O, comprises one chloridobis(ethyl­enediamine)(n-pentyl­amine)cobalt(III) cation, two chloride counter-anions and a water mol­ecule. The Co(III) atom of the complex is hexa­coordinated by five N and one Cl atoms. The five N atoms are from two chelating ethyl­enediamine and one n-pentyl­amine ligands. Neighbouring cations and anions are connected by N—H⋯Cl and N—H⋯O hydrogen bonds to each other and also to the water mol­ecule.
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spelling pubmed-29694822010-12-30 Chloridobis(ethyl­enediamine-κ(2) N,N′)(n-pentyl­amine-κN)cobalt(III) dichloride monhydrate Anbalagan, K. Tamilselvan, M. Nirmala, S. Sudha, L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [CoCl(C(5)H(13)N)(C(2)H(8)N(2))(2)]Cl(2)·H(2)O, comprises one chloridobis(ethyl­enediamine)(n-pentyl­amine)cobalt(III) cation, two chloride counter-anions and a water mol­ecule. The Co(III) atom of the complex is hexa­coordinated by five N and one Cl atoms. The five N atoms are from two chelating ethyl­enediamine and one n-pentyl­amine ligands. Neighbouring cations and anions are connected by N—H⋯Cl and N—H⋯O hydrogen bonds to each other and also to the water mol­ecule. International Union of Crystallography 2009-06-27 /pmc/articles/PMC2969482/ /pubmed/21582753 http://dx.doi.org/10.1107/S1600536809022764 Text en © Anbalagan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Anbalagan, K.
Tamilselvan, M.
Nirmala, S.
Sudha, L.
Chloridobis(ethyl­enediamine-κ(2) N,N′)(n-pentyl­amine-κN)cobalt(III) dichloride monhydrate
title Chloridobis(ethyl­enediamine-κ(2) N,N′)(n-pentyl­amine-κN)cobalt(III) dichloride monhydrate
title_full Chloridobis(ethyl­enediamine-κ(2) N,N′)(n-pentyl­amine-κN)cobalt(III) dichloride monhydrate
title_fullStr Chloridobis(ethyl­enediamine-κ(2) N,N′)(n-pentyl­amine-κN)cobalt(III) dichloride monhydrate
title_full_unstemmed Chloridobis(ethyl­enediamine-κ(2) N,N′)(n-pentyl­amine-κN)cobalt(III) dichloride monhydrate
title_short Chloridobis(ethyl­enediamine-κ(2) N,N′)(n-pentyl­amine-κN)cobalt(III) dichloride monhydrate
title_sort chloridobis(ethyl­enediamine-κ(2) n,n′)(n-pentyl­amine-κn)cobalt(iii) dichloride monhydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969482/
https://www.ncbi.nlm.nih.gov/pubmed/21582753
http://dx.doi.org/10.1107/S1600536809022764
work_keys_str_mv AT anbalagank chloridobisethylenediaminek2nnnpentylaminekncobaltiiidichloridemonhydrate
AT tamilselvanm chloridobisethylenediaminek2nnnpentylaminekncobaltiiidichloridemonhydrate
AT nirmalas chloridobisethylenediaminek2nnnpentylaminekncobaltiiidichloridemonhydrate
AT sudhal chloridobisethylenediaminek2nnnpentylaminekncobaltiiidichloridemonhydrate

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