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Poly[[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)zinc(II)] monohydrate]

The three-dimensional polymeric title compound, {[Zn(C(9)H(4)N(2)O(4))]·H(2)O}(n), contains one crystallographically independent Zn(II) atom, one fully deprotonated 1H-benzimid­azole-5,6-dicarboxyl­ate (bdc) ligand and one uncoordinated water mol­ecule. The Zn(II) atom is four-coordinated by three O...

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Detalles Bibliográficos
Autores principales: Li, Zhao-yang, Dai, Jing-wei, Yue, Shan-tang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969483/
https://www.ncbi.nlm.nih.gov/pubmed/21582705
http://dx.doi.org/10.1107/S1600536809022107
Descripción
Sumario:The three-dimensional polymeric title compound, {[Zn(C(9)H(4)N(2)O(4))]·H(2)O}(n), contains one crystallographically independent Zn(II) atom, one fully deprotonated 1H-benzimid­azole-5,6-dicarboxyl­ate (bdc) ligand and one uncoordinated water mol­ecule. The Zn(II) atom is four-coordinated by three O atoms and one N atom from the bdc ligands, giving a distorted tetra­hedral coordination geometry. The uncoordinated water mol­ecule is bound to the main structure through a strong bdc–water N—H⋯O hydrogen bond, and two much weaker water–bdc O—H⋯O inter­actions.