Poly[[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)zinc(II)] monohydrate]

The three-dimensional polymeric title compound, {[Zn(C(9)H(4)N(2)O(4))]·H(2)O}(n), contains one crystallographically independent Zn(II) atom, one fully deprotonated 1H-benzimid­azole-5,6-dicarboxyl­ate (bdc) ligand and one uncoordinated water mol­ecule. The Zn(II) atom is four-coordinated by three O...

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Detalles Bibliográficos
Autores principales: Li, Zhao-yang, Dai, Jing-wei, Yue, Shan-tang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969483/
https://www.ncbi.nlm.nih.gov/pubmed/21582705
http://dx.doi.org/10.1107/S1600536809022107
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author Li, Zhao-yang
Dai, Jing-wei
Yue, Shan-tang
author_facet Li, Zhao-yang
Dai, Jing-wei
Yue, Shan-tang
author_sort Li, Zhao-yang
collection PubMed
description The three-dimensional polymeric title compound, {[Zn(C(9)H(4)N(2)O(4))]·H(2)O}(n), contains one crystallographically independent Zn(II) atom, one fully deprotonated 1H-benzimid­azole-5,6-dicarboxyl­ate (bdc) ligand and one uncoordinated water mol­ecule. The Zn(II) atom is four-coordinated by three O atoms and one N atom from the bdc ligands, giving a distorted tetra­hedral coordination geometry. The uncoordinated water mol­ecule is bound to the main structure through a strong bdc–water N—H⋯O hydrogen bond, and two much weaker water–bdc O—H⋯O inter­actions.
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spelling pubmed-29694832010-12-30 Poly[[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)zinc(II)] monohydrate] Li, Zhao-yang Dai, Jing-wei Yue, Shan-tang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The three-dimensional polymeric title compound, {[Zn(C(9)H(4)N(2)O(4))]·H(2)O}(n), contains one crystallographically independent Zn(II) atom, one fully deprotonated 1H-benzimid­azole-5,6-dicarboxyl­ate (bdc) ligand and one uncoordinated water mol­ecule. The Zn(II) atom is four-coordinated by three O atoms and one N atom from the bdc ligands, giving a distorted tetra­hedral coordination geometry. The uncoordinated water mol­ecule is bound to the main structure through a strong bdc–water N—H⋯O hydrogen bond, and two much weaker water–bdc O—H⋯O inter­actions. International Union of Crystallography 2009-06-13 /pmc/articles/PMC2969483/ /pubmed/21582705 http://dx.doi.org/10.1107/S1600536809022107 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Zhao-yang
Dai, Jing-wei
Yue, Shan-tang
Poly[[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)zinc(II)] monohydrate]
title Poly[[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)zinc(II)] monohydrate]
title_full Poly[[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)zinc(II)] monohydrate]
title_fullStr Poly[[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)zinc(II)] monohydrate]
title_full_unstemmed Poly[[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)zinc(II)] monohydrate]
title_short Poly[[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)zinc(II)] monohydrate]
title_sort poly[[(μ-1h-benzimidazole-5,6-dicarboxyl­ato)zinc(ii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969483/
https://www.ncbi.nlm.nih.gov/pubmed/21582705
http://dx.doi.org/10.1107/S1600536809022107
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