Cargando…

catena-Poly[[bis­(4-carboxy­cyclo­hexane­carboxyl­ato-κ(2) O (1),O (1′))cadmium(II)]-μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]

In the title coordination polymer, [Cd(C(8)H(11)O(4))(2)(C(14)H(14)N(4))](n), the Cd atom (site symmetry 2) is six-coordin­ated by two O,O′-bidentate 4-carboxy­cyclo­hexa­necarboxyl­ate (Hchdc) ligands and two N atoms from two different 1,4-bis­(imidazol-1-ylmeth­yl)benzene (1,4-bix) mol­ecules in a...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Bing-Bing, Xiao, Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969484/
https://www.ncbi.nlm.nih.gov/pubmed/21582692
http://dx.doi.org/10.1107/S1600536809021618
_version_ 1782190164579188736
author Li, Bing-Bing
Xiao, Bo
author_facet Li, Bing-Bing
Xiao, Bo
author_sort Li, Bing-Bing
collection PubMed
description In the title coordination polymer, [Cd(C(8)H(11)O(4))(2)(C(14)H(14)N(4))](n), the Cd atom (site symmetry 2) is six-coordin­ated by two O,O′-bidentate 4-carboxy­cyclo­hexa­necarboxyl­ate (Hchdc) ligands and two N atoms from two different 1,4-bis­(imidazol-1-ylmeth­yl)benzene (1,4-bix) mol­ecules in a very distorted cis-CdN(2)O(4) octa­hedral environment. The 1,4-bix mol­ecules act as bridging ligands that bind two Cd(II) atoms, thus forming an infinite chain propagating in [100], which is decorated by the Hchdc anions. The structure is completed by O—H⋯O hydrogen bonds, which link the chains together.
format Text
id pubmed-2969484
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29694842010-12-30 catena-Poly[[bis­(4-carboxy­cyclo­hexane­carboxyl­ato-κ(2) O (1),O (1′))cadmium(II)]-μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)] Li, Bing-Bing Xiao, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cd(C(8)H(11)O(4))(2)(C(14)H(14)N(4))](n), the Cd atom (site symmetry 2) is six-coordin­ated by two O,O′-bidentate 4-carboxy­cyclo­hexa­necarboxyl­ate (Hchdc) ligands and two N atoms from two different 1,4-bis­(imidazol-1-ylmeth­yl)benzene (1,4-bix) mol­ecules in a very distorted cis-CdN(2)O(4) octa­hedral environment. The 1,4-bix mol­ecules act as bridging ligands that bind two Cd(II) atoms, thus forming an infinite chain propagating in [100], which is decorated by the Hchdc anions. The structure is completed by O—H⋯O hydrogen bonds, which link the chains together. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969484/ /pubmed/21582692 http://dx.doi.org/10.1107/S1600536809021618 Text en © Li and Xiao 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Bing-Bing
Xiao, Bo
catena-Poly[[bis­(4-carboxy­cyclo­hexane­carboxyl­ato-κ(2) O (1),O (1′))cadmium(II)]-μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]
title catena-Poly[[bis­(4-carboxy­cyclo­hexane­carboxyl­ato-κ(2) O (1),O (1′))cadmium(II)]-μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]
title_full catena-Poly[[bis­(4-carboxy­cyclo­hexane­carboxyl­ato-κ(2) O (1),O (1′))cadmium(II)]-μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]
title_fullStr catena-Poly[[bis­(4-carboxy­cyclo­hexane­carboxyl­ato-κ(2) O (1),O (1′))cadmium(II)]-μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]
title_full_unstemmed catena-Poly[[bis­(4-carboxy­cyclo­hexane­carboxyl­ato-κ(2) O (1),O (1′))cadmium(II)]-μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]
title_short catena-Poly[[bis­(4-carboxy­cyclo­hexane­carboxyl­ato-κ(2) O (1),O (1′))cadmium(II)]-μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]
title_sort catena-poly[[bis­(4-carboxy­cyclo­hexane­carboxyl­ato-κ(2) o (1),o (1′))cadmium(ii)]-μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) n (3):n (3′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969484/
https://www.ncbi.nlm.nih.gov/pubmed/21582692
http://dx.doi.org/10.1107/S1600536809021618
work_keys_str_mv AT libingbing catenapolybis4carboxycyclohexanecarboxylatok2o1o1cadmiumiim14bisimidazol1ylmethylbenzenek2n3n3
AT xiaobo catenapolybis4carboxycyclohexanecarboxylatok2o1o1cadmiumiim14bisimidazol1ylmethylbenzenek2n3n3