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catena-Poly[[bis(4-carboxycyclohexanecarboxylato-κ(2) O (1),O (1′))cadmium(II)]-μ-1,4-bis(imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)]
In the title coordination polymer, [Cd(C(8)H(11)O(4))(2)(C(14)H(14)N(4))](n), the Cd atom (site symmetry 2) is six-coordinated by two O,O′-bidentate 4-carboxycyclohexanecarboxylate (Hchdc) ligands and two N atoms from two different 1,4-bis(imidazol-1-ylmethyl)benzene (1,4-bix) molecules in a...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969484/ https://www.ncbi.nlm.nih.gov/pubmed/21582692 http://dx.doi.org/10.1107/S1600536809021618 |
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author | Li, Bing-Bing Xiao, Bo |
author_facet | Li, Bing-Bing Xiao, Bo |
author_sort | Li, Bing-Bing |
collection | PubMed |
description | In the title coordination polymer, [Cd(C(8)H(11)O(4))(2)(C(14)H(14)N(4))](n), the Cd atom (site symmetry 2) is six-coordinated by two O,O′-bidentate 4-carboxycyclohexanecarboxylate (Hchdc) ligands and two N atoms from two different 1,4-bis(imidazol-1-ylmethyl)benzene (1,4-bix) molecules in a very distorted cis-CdN(2)O(4) octahedral environment. The 1,4-bix molecules act as bridging ligands that bind two Cd(II) atoms, thus forming an infinite chain propagating in [100], which is decorated by the Hchdc anions. The structure is completed by O—H⋯O hydrogen bonds, which link the chains together. |
format | Text |
id | pubmed-2969484 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29694842010-12-30 catena-Poly[[bis(4-carboxycyclohexanecarboxylato-κ(2) O (1),O (1′))cadmium(II)]-μ-1,4-bis(imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)] Li, Bing-Bing Xiao, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cd(C(8)H(11)O(4))(2)(C(14)H(14)N(4))](n), the Cd atom (site symmetry 2) is six-coordinated by two O,O′-bidentate 4-carboxycyclohexanecarboxylate (Hchdc) ligands and two N atoms from two different 1,4-bis(imidazol-1-ylmethyl)benzene (1,4-bix) molecules in a very distorted cis-CdN(2)O(4) octahedral environment. The 1,4-bix molecules act as bridging ligands that bind two Cd(II) atoms, thus forming an infinite chain propagating in [100], which is decorated by the Hchdc anions. The structure is completed by O—H⋯O hydrogen bonds, which link the chains together. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969484/ /pubmed/21582692 http://dx.doi.org/10.1107/S1600536809021618 Text en © Li and Xiao 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Bing-Bing Xiao, Bo catena-Poly[[bis(4-carboxycyclohexanecarboxylato-κ(2) O (1),O (1′))cadmium(II)]-μ-1,4-bis(imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)] |
title |
catena-Poly[[bis(4-carboxycyclohexanecarboxylato-κ(2)
O
(1),O
(1′))cadmium(II)]-μ-1,4-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)] |
title_full |
catena-Poly[[bis(4-carboxycyclohexanecarboxylato-κ(2)
O
(1),O
(1′))cadmium(II)]-μ-1,4-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)] |
title_fullStr |
catena-Poly[[bis(4-carboxycyclohexanecarboxylato-κ(2)
O
(1),O
(1′))cadmium(II)]-μ-1,4-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)] |
title_full_unstemmed |
catena-Poly[[bis(4-carboxycyclohexanecarboxylato-κ(2)
O
(1),O
(1′))cadmium(II)]-μ-1,4-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)] |
title_short |
catena-Poly[[bis(4-carboxycyclohexanecarboxylato-κ(2)
O
(1),O
(1′))cadmium(II)]-μ-1,4-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)] |
title_sort | catena-poly[[bis(4-carboxycyclohexanecarboxylato-κ(2)
o
(1),o
(1′))cadmium(ii)]-μ-1,4-bis(imidazol-1-ylmethyl)benzene-κ(2)
n
(3):n
(3′)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969484/ https://www.ncbi.nlm.nih.gov/pubmed/21582692 http://dx.doi.org/10.1107/S1600536809021618 |
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