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2-[(E)-2-(4-Chlorophenyl)ethenyl]-1-methylpyridinium 4-chlorobenzenesulfonate
In the title salt, C(14)H(13)ClN(+)·C(6)H(4)ClO(3)S(−), the cation exists in an E configuration with respect to the ethynyl bond and is approximately planar, with a dihedral angle of 3.4 (2)° between the pyridinium and benzene rings. The anion is approximately perpendicular to the cation plane, the...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969486/ https://www.ncbi.nlm.nih.gov/pubmed/21582839 http://dx.doi.org/10.1107/S1600536809021667 |
Sumario: | In the title salt, C(14)H(13)ClN(+)·C(6)H(4)ClO(3)S(−), the cation exists in an E configuration with respect to the ethynyl bond and is approximately planar, with a dihedral angle of 3.4 (2)° between the pyridinium and benzene rings. The anion is approximately perpendicular to the cation plane, the benzene ring of the anion making dihedral angles of 89.4 (2) and 89.9 (2)°, respectively, with the pyridinium and benzene rings of the cation. In the crystal structure, the cations are linked into a chain along the c axis by C—H⋯Cl interactions. The anions are linked to the adjacent cation chains by C—H⋯O and C—H⋯Cl interactions, forming a two-dimensional network parallel to the bc plane. The crystal structure is further stabilized by C—H⋯π interactions. A π–π interaction is also observed between the pyridinium ring and the benzene ring of the cation with a centroid–centroid distance of 3.668 (3) Å. |
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