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2-Methoxy-6-(6-methyl-1H-benzimidazol-2-yl)phenol
In the title molecule, C(15)H(14)N(2)O(2), the substituted benzene ring forms a dihedral angle of 4.15 (1)° with the benzimidazole ring system. An intramolecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the solid state, molecules are linked into chains along the [001] via intermolecu...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969490/ https://www.ncbi.nlm.nih.gov/pubmed/21582885 http://dx.doi.org/10.1107/S1600536809022478 |
Sumario: | In the title molecule, C(15)H(14)N(2)O(2), the substituted benzene ring forms a dihedral angle of 4.15 (1)° with the benzimidazole ring system. An intramolecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the solid state, molecules are linked into chains along the [001] via intermolecular bifurcated N—H⋯(O,O) hydrogen bonds, which generate R (1) (2)(5) ring motifs. The crystal packing is also consolidated by C—H⋯π interactions, and π–π stacking interactions between the imidazole and substituted benzene rings [centroid–centroid distance = 3.5746 (13) Å]. The methyl group attached to the benzimidazole ring system is disordered over two positions with occupancies of 0.587 (6) and 0.413 (6), suggesting 180° rotational disorder for the benzimidazole group. |
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