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catena-Poly[[diaqua­bis(thio­cyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 4,4′-bipyridine solvate]

In the title complex, {[Co(NCS)(2)(C(10)H(8)N(2))(H(2)O)(2)]·C(10)H(8)N(2)}(n), the Co(II) ion is located on an inversion centre and is coordinated by two N atoms from the two 4,4′-bipyridine ligands, two O atoms from the water mol­ecule, and two N atoms from two isothio­cyanate ions in a distorted...

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Detalles Bibliográficos
Autores principales: Yao, Rufu, Wang, Dong E.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969491/
https://www.ncbi.nlm.nih.gov/pubmed/21582736
http://dx.doi.org/10.1107/S1600536809023265
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author Yao, Rufu
Wang, Dong E.
author_facet Yao, Rufu
Wang, Dong E.
author_sort Yao, Rufu
collection PubMed
description In the title complex, {[Co(NCS)(2)(C(10)H(8)N(2))(H(2)O)(2)]·C(10)H(8)N(2)}(n), the Co(II) ion is located on an inversion centre and is coordinated by two N atoms from the two 4,4′-bipyridine ligands, two O atoms from the water mol­ecule, and two N atoms from two isothio­cyanate ions in a distorted octa­hedral environment. In the crystal, the coordinated water mol­ecules, isothio­cyanate ions and solvent 4,4′-bipyridine mol­ecules are linked by O—H⋯S and O—H⋯N hydrogen bonds into layers parallel to the ab plane.
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spelling pubmed-29694912010-12-30 catena-Poly[[diaqua­bis(thio­cyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 4,4′-bipyridine solvate] Yao, Rufu Wang, Dong E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Co(NCS)(2)(C(10)H(8)N(2))(H(2)O)(2)]·C(10)H(8)N(2)}(n), the Co(II) ion is located on an inversion centre and is coordinated by two N atoms from the two 4,4′-bipyridine ligands, two O atoms from the water mol­ecule, and two N atoms from two isothio­cyanate ions in a distorted octa­hedral environment. In the crystal, the coordinated water mol­ecules, isothio­cyanate ions and solvent 4,4′-bipyridine mol­ecules are linked by O—H⋯S and O—H⋯N hydrogen bonds into layers parallel to the ab plane. International Union of Crystallography 2009-06-24 /pmc/articles/PMC2969491/ /pubmed/21582736 http://dx.doi.org/10.1107/S1600536809023265 Text en © Yao and Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yao, Rufu
Wang, Dong E.
catena-Poly[[diaqua­bis(thio­cyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 4,4′-bipyridine solvate]
title catena-Poly[[diaqua­bis(thio­cyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 4,4′-bipyridine solvate]
title_full catena-Poly[[diaqua­bis(thio­cyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 4,4′-bipyridine solvate]
title_fullStr catena-Poly[[diaqua­bis(thio­cyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 4,4′-bipyridine solvate]
title_full_unstemmed catena-Poly[[diaqua­bis(thio­cyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 4,4′-bipyridine solvate]
title_short catena-Poly[[diaqua­bis(thio­cyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 4,4′-bipyridine solvate]
title_sort catena-poly[[diaqua­bis(thio­cyanato-κn)cobalt(ii)]-μ-4,4′-bipyridine-κ(2) n:n′] 4,4′-bipyridine solvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969491/
https://www.ncbi.nlm.nih.gov/pubmed/21582736
http://dx.doi.org/10.1107/S1600536809023265
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