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catena-Poly[[diaquabis(thiocyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 4,4′-bipyridine solvate]
In the title complex, {[Co(NCS)(2)(C(10)H(8)N(2))(H(2)O)(2)]·C(10)H(8)N(2)}(n), the Co(II) ion is located on an inversion centre and is coordinated by two N atoms from the two 4,4′-bipyridine ligands, two O atoms from the water molecule, and two N atoms from two isothiocyanate ions in a distorted...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969491/ https://www.ncbi.nlm.nih.gov/pubmed/21582736 http://dx.doi.org/10.1107/S1600536809023265 |
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author | Yao, Rufu Wang, Dong E. |
author_facet | Yao, Rufu Wang, Dong E. |
author_sort | Yao, Rufu |
collection | PubMed |
description | In the title complex, {[Co(NCS)(2)(C(10)H(8)N(2))(H(2)O)(2)]·C(10)H(8)N(2)}(n), the Co(II) ion is located on an inversion centre and is coordinated by two N atoms from the two 4,4′-bipyridine ligands, two O atoms from the water molecule, and two N atoms from two isothiocyanate ions in a distorted octahedral environment. In the crystal, the coordinated water molecules, isothiocyanate ions and solvent 4,4′-bipyridine molecules are linked by O—H⋯S and O—H⋯N hydrogen bonds into layers parallel to the ab plane. |
format | Text |
id | pubmed-2969491 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29694912010-12-30 catena-Poly[[diaquabis(thiocyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 4,4′-bipyridine solvate] Yao, Rufu Wang, Dong E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Co(NCS)(2)(C(10)H(8)N(2))(H(2)O)(2)]·C(10)H(8)N(2)}(n), the Co(II) ion is located on an inversion centre and is coordinated by two N atoms from the two 4,4′-bipyridine ligands, two O atoms from the water molecule, and two N atoms from two isothiocyanate ions in a distorted octahedral environment. In the crystal, the coordinated water molecules, isothiocyanate ions and solvent 4,4′-bipyridine molecules are linked by O—H⋯S and O—H⋯N hydrogen bonds into layers parallel to the ab plane. International Union of Crystallography 2009-06-24 /pmc/articles/PMC2969491/ /pubmed/21582736 http://dx.doi.org/10.1107/S1600536809023265 Text en © Yao and Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yao, Rufu Wang, Dong E. catena-Poly[[diaquabis(thiocyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 4,4′-bipyridine solvate] |
title |
catena-Poly[[diaquabis(thiocyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] 4,4′-bipyridine solvate] |
title_full |
catena-Poly[[diaquabis(thiocyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] 4,4′-bipyridine solvate] |
title_fullStr |
catena-Poly[[diaquabis(thiocyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] 4,4′-bipyridine solvate] |
title_full_unstemmed |
catena-Poly[[diaquabis(thiocyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] 4,4′-bipyridine solvate] |
title_short |
catena-Poly[[diaquabis(thiocyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] 4,4′-bipyridine solvate] |
title_sort | catena-poly[[diaquabis(thiocyanato-κn)cobalt(ii)]-μ-4,4′-bipyridine-κ(2)
n:n′] 4,4′-bipyridine solvate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969491/ https://www.ncbi.nlm.nih.gov/pubmed/21582736 http://dx.doi.org/10.1107/S1600536809023265 |
work_keys_str_mv | AT yaorufu catenapolydiaquabisthiocyanatokncobaltiim44bipyridinek2nn44bipyridinesolvate AT wangdonge catenapolydiaquabisthiocyanatokncobaltiim44bipyridinek2nn44bipyridinesolvate |