[5-Chloro-2-hydroxy-N′-(2-oxido­ben­zyl­idene)benzo­hy­dra­zidato]­pyridine­copper(II)

In the title complex, [Cu(C(14)H(9)ClN(2)O(3))(C(5)H(5)N)], the Cu(II) ion exhibits a distorted trans-CuN(2)O(2) square-planar geometry arising from the O,O,N-tridentate ligand and a pyridine mol­ecule. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal structure, weak inter­molecular C—H...

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Detalles Bibliográficos
Autores principales: Li, Piyong, Li, Dacheng, Shi, Xuefeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969500/
https://www.ncbi.nlm.nih.gov/pubmed/21582679
http://dx.doi.org/10.1107/S1600536809020546
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author Li, Piyong
Li, Dacheng
Shi, Xuefeng
author_facet Li, Piyong
Li, Dacheng
Shi, Xuefeng
author_sort Li, Piyong
collection PubMed
description In the title complex, [Cu(C(14)H(9)ClN(2)O(3))(C(5)H(5)N)], the Cu(II) ion exhibits a distorted trans-CuN(2)O(2) square-planar geometry arising from the O,O,N-tridentate ligand and a pyridine mol­ecule. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal structure, weak inter­molecular C—H⋯π inter­actions generate a chain. The crystal studied was an inversion twin.
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spelling pubmed-29695002010-12-30 [5-Chloro-2-hydroxy-N′-(2-oxido­ben­zyl­idene)benzo­hy­dra­zidato]­pyridine­copper(II) Li, Piyong Li, Dacheng Shi, Xuefeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(14)H(9)ClN(2)O(3))(C(5)H(5)N)], the Cu(II) ion exhibits a distorted trans-CuN(2)O(2) square-planar geometry arising from the O,O,N-tridentate ligand and a pyridine mol­ecule. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal structure, weak inter­molecular C—H⋯π inter­actions generate a chain. The crystal studied was an inversion twin. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969500/ /pubmed/21582679 http://dx.doi.org/10.1107/S1600536809020546 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Piyong
Li, Dacheng
Shi, Xuefeng
[5-Chloro-2-hydroxy-N′-(2-oxido­ben­zyl­idene)benzo­hy­dra­zidato]­pyridine­copper(II)
title [5-Chloro-2-hydroxy-N′-(2-oxido­ben­zyl­idene)benzo­hy­dra­zidato]­pyridine­copper(II)
title_full [5-Chloro-2-hydroxy-N′-(2-oxido­ben­zyl­idene)benzo­hy­dra­zidato]­pyridine­copper(II)
title_fullStr [5-Chloro-2-hydroxy-N′-(2-oxido­ben­zyl­idene)benzo­hy­dra­zidato]­pyridine­copper(II)
title_full_unstemmed [5-Chloro-2-hydroxy-N′-(2-oxido­ben­zyl­idene)benzo­hy­dra­zidato]­pyridine­copper(II)
title_short [5-Chloro-2-hydroxy-N′-(2-oxido­ben­zyl­idene)benzo­hy­dra­zidato]­pyridine­copper(II)
title_sort [5-chloro-2-hydroxy-n′-(2-oxido­ben­zyl­idene)benzo­hy­dra­zidato]­pyridine­copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969500/
https://www.ncbi.nlm.nih.gov/pubmed/21582679
http://dx.doi.org/10.1107/S1600536809020546
work_keys_str_mv AT lipiyong 5chloro2hydroxyn2oxidobenzylidenebenzohydrazidatopyridinecopperii
AT lidacheng 5chloro2hydroxyn2oxidobenzylidenebenzohydrazidatopyridinecopperii
AT shixuefeng 5chloro2hydroxyn2oxidobenzylidenebenzohydrazidatopyridinecopperii

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