Bis(4-amino­benzene­sulfonato-κN)diaqua­bis(dimethyl­formamide-κO)nickel(II) dihydrate

In the title compound, [Ni(C(6)H(6)NO(3)S)(2)(C(3)H(7)NO)(2)(H(2)O)(2)]·2H(2)O, the Ni(II) ion (site symmetry [Image: see text]) is coordinated by two –NH(2) groups from two 4-amino­benzene­sulfonate anions, two O atoms from two dimethyl­formamide mol­ecules and two water mol­ecules, forming a sligh...

Descripción completa

Detalles Bibliográficos
Autores principales: Tan, Jun, He, Ya-Ping, Bao, Xiao-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969510/
https://www.ncbi.nlm.nih.gov/pubmed/21582668
http://dx.doi.org/10.1107/S1600536809020406
Descripción
Sumario:In the title compound, [Ni(C(6)H(6)NO(3)S)(2)(C(3)H(7)NO)(2)(H(2)O)(2)]·2H(2)O, the Ni(II) ion (site symmetry [Image: see text]) is coordinated by two –NH(2) groups from two 4-amino­benzene­sulfonate anions, two O atoms from two dimethyl­formamide mol­ecules and two water mol­ecules, forming a slightly distorted trans-NiN(2)O(4) octa­hedral geometry. In the crystal structure, inter­molecular O—H⋯O, O—H⋯(O,O) and N—H⋯O hydrogen bonds link the components into a three-dimensional network. The O atoms of the sulfonate group are disordered over two sets of sites in a 0.833 (4):0.167 (4) ratio and the O atom of the uncoordinated water mol­ecule is disordered over two sites in a 0.637 (18):0.363 (18) ratio.

Ejemplares similares