Bis[μ-1,1′-(ferrocene-1,1′-di­yl)bis(butane-1,3-dionato)]di-μ-methanol-diiron(II)

The asymmetric unit of the title compound, [Fe(4)(C(9)H(8)O(2))(4)(CH(3)OH)(2)], contains one half-mol­ecule located on a twofold rotational axis. In the mol­ecule, the two Fe(II) ions bridged by two coordinating methanol mol­ecules are separated by 3.1286 (7) Å. Two crystallographically independent...

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Detalles Bibliográficos
Autores principales: Xiao, Yan-Feng, Li, Hong-Feng, Yan, Peng-Fei, Li, Guang-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969521/
https://www.ncbi.nlm.nih.gov/pubmed/21582994
http://dx.doi.org/10.1107/S1600536809016353
Descripción
Sumario:The asymmetric unit of the title compound, [Fe(4)(C(9)H(8)O(2))(4)(CH(3)OH)(2)], contains one half-mol­ecule located on a twofold rotational axis. In the mol­ecule, the two Fe(II) ions bridged by two coordinating methanol mol­ecules are separated by 3.1286 (7) Å. Two crystallographically independent methanol mol­ecules are situated on a twofold rotational axis; all attached H atoms are rotationally disordered between two equal orientations.

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