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2,4-Bis(2-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one

In the title compound, C(22)H(25)NO(3), the mol­ecule has a pseudo-mirror plane. The structure is a positional isomer of 2,4-bis(4-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one [Cox, McCabe, Milne & Sim (1985 ▶). J. Chem. Soc. Chem. Commun. pp. 626–628]. The 3-aza­bicyclo­[3.3.1]nonan-9-one m...

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Detalles Bibliográficos
Autores principales: Parthiban, P., Ramkumar, V., Kim, Min Sung, Son, Se Mo, Jeong, Yeon Tae
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969524/
https://www.ncbi.nlm.nih.gov/pubmed/21583231
http://dx.doi.org/10.1107/S1600536809018686
Descripción
Sumario:In the title compound, C(22)H(25)NO(3), the mol­ecule has a pseudo-mirror plane. The structure is a positional isomer of 2,4-bis(4-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one [Cox, McCabe, Milne & Sim (1985 ▶). J. Chem. Soc. Chem. Commun. pp. 626–628]. The 3-aza­bicyclo­[3.3.1]nonan-9-one moiety adopts a double chair conformation with equatorial orientations of both 2-methoxy­phenyl substituents on either side of the secondary amino group. The benzene rings are oriented at an angle of 33.86 (4)° with respect to each other and the meth­oxy groups point towards the carbonyl group. The crystal structure is stabilized by intermolecular N—H⋯π inter­actions.