2,4-Bis(2-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one

In the title compound, C(22)H(25)NO(3), the mol­ecule has a pseudo-mirror plane. The structure is a positional isomer of 2,4-bis(4-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one [Cox, McCabe, Milne & Sim (1985 ▶). J. Chem. Soc. Chem. Commun. pp. 626–628]. The 3-aza­bicyclo­[3.3.1]nonan-9-one m...

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Detalles Bibliográficos
Autores principales: Parthiban, P., Ramkumar, V., Kim, Min Sung, Son, Se Mo, Jeong, Yeon Tae
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969524/
https://www.ncbi.nlm.nih.gov/pubmed/21583231
http://dx.doi.org/10.1107/S1600536809018686
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author Parthiban, P.
Ramkumar, V.
Kim, Min Sung
Son, Se Mo
Jeong, Yeon Tae
author_facet Parthiban, P.
Ramkumar, V.
Kim, Min Sung
Son, Se Mo
Jeong, Yeon Tae
author_sort Parthiban, P.
collection PubMed
description In the title compound, C(22)H(25)NO(3), the mol­ecule has a pseudo-mirror plane. The structure is a positional isomer of 2,4-bis(4-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one [Cox, McCabe, Milne & Sim (1985 ▶). J. Chem. Soc. Chem. Commun. pp. 626–628]. The 3-aza­bicyclo­[3.3.1]nonan-9-one moiety adopts a double chair conformation with equatorial orientations of both 2-methoxy­phenyl substituents on either side of the secondary amino group. The benzene rings are oriented at an angle of 33.86 (4)° with respect to each other and the meth­oxy groups point towards the carbonyl group. The crystal structure is stabilized by intermolecular N—H⋯π inter­actions.
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spelling pubmed-29695242010-12-30 2,4-Bis(2-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one Parthiban, P. Ramkumar, V. Kim, Min Sung Son, Se Mo Jeong, Yeon Tae Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(25)NO(3), the mol­ecule has a pseudo-mirror plane. The structure is a positional isomer of 2,4-bis(4-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one [Cox, McCabe, Milne & Sim (1985 ▶). J. Chem. Soc. Chem. Commun. pp. 626–628]. The 3-aza­bicyclo­[3.3.1]nonan-9-one moiety adopts a double chair conformation with equatorial orientations of both 2-methoxy­phenyl substituents on either side of the secondary amino group. The benzene rings are oriented at an angle of 33.86 (4)° with respect to each other and the meth­oxy groups point towards the carbonyl group. The crystal structure is stabilized by intermolecular N—H⋯π inter­actions. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969524/ /pubmed/21583231 http://dx.doi.org/10.1107/S1600536809018686 Text en © Parthiban et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Parthiban, P.
Ramkumar, V.
Kim, Min Sung
Son, Se Mo
Jeong, Yeon Tae
2,4-Bis(2-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one
title 2,4-Bis(2-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one
title_full 2,4-Bis(2-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one
title_fullStr 2,4-Bis(2-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one
title_full_unstemmed 2,4-Bis(2-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one
title_short 2,4-Bis(2-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one
title_sort 2,4-bis(2-methoxy­phenyl)-3-aza­bicyclo­[3.3.1]nonan-9-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969524/
https://www.ncbi.nlm.nih.gov/pubmed/21583231
http://dx.doi.org/10.1107/S1600536809018686
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