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Triphenylbis[4-(trifluoromethyl)benzoato-κO]antimony(V)
The title complex, [Sb(C(6)H(5))(3)(C(8)H(4)F(3)O(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The environment of the Sb atom approximates a trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969530/ https://www.ncbi.nlm.nih.gov/pubmed/21583020 http://dx.doi.org/10.1107/S1600536809017449 |
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author | Quan, Li Yin, Handong Cui, Liansheng Yang, Minglei Wang, Daqi |
author_facet | Quan, Li Yin, Handong Cui, Liansheng Yang, Minglei Wang, Daqi |
author_sort | Quan, Li |
collection | PubMed |
description | The title complex, [Sb(C(6)H(5))(3)(C(8)H(4)F(3)O(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The environment of the Sb atom approximates a trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry-related 4-(trifluoromethyl)benzoate ligands. In this ligand, the CF(3) group is disordered by rotation about the C—C bond and the F atoms are distributed over two sets of sites with occupancies of 0.62 (3) and 0.38 (3). In the crystal, molecules are assembled in a three-dimensional framework through weak C—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2969530 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29695302010-12-30 Triphenylbis[4-(trifluoromethyl)benzoato-κO]antimony(V) Quan, Li Yin, Handong Cui, Liansheng Yang, Minglei Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Sb(C(6)H(5))(3)(C(8)H(4)F(3)O(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The environment of the Sb atom approximates a trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry-related 4-(trifluoromethyl)benzoate ligands. In this ligand, the CF(3) group is disordered by rotation about the C—C bond and the F atoms are distributed over two sets of sites with occupancies of 0.62 (3) and 0.38 (3). In the crystal, molecules are assembled in a three-dimensional framework through weak C—H⋯O hydrogen bonds. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969530/ /pubmed/21583020 http://dx.doi.org/10.1107/S1600536809017449 Text en © Quan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Quan, Li Yin, Handong Cui, Liansheng Yang, Minglei Wang, Daqi Triphenylbis[4-(trifluoromethyl)benzoato-κO]antimony(V) |
title | Triphenylbis[4-(trifluoromethyl)benzoato-κO]antimony(V) |
title_full | Triphenylbis[4-(trifluoromethyl)benzoato-κO]antimony(V) |
title_fullStr | Triphenylbis[4-(trifluoromethyl)benzoato-κO]antimony(V) |
title_full_unstemmed | Triphenylbis[4-(trifluoromethyl)benzoato-κO]antimony(V) |
title_short | Triphenylbis[4-(trifluoromethyl)benzoato-κO]antimony(V) |
title_sort | triphenylbis[4-(trifluoromethyl)benzoato-κo]antimony(v) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969530/ https://www.ncbi.nlm.nih.gov/pubmed/21583020 http://dx.doi.org/10.1107/S1600536809017449 |
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