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Triphenyl­bis[4-(trifluoro­meth­yl)benzoato-κO]anti­mony(V)

The title complex, [Sb(C(6)H(5))(3)(C(8)H(4)F(3)O(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The environment of the Sb atom approximates a trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry...

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Detalles Bibliográficos
Autores principales: Quan, Li, Yin, Handong, Cui, Liansheng, Yang, Minglei, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969530/
https://www.ncbi.nlm.nih.gov/pubmed/21583020
http://dx.doi.org/10.1107/S1600536809017449
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author Quan, Li
Yin, Handong
Cui, Liansheng
Yang, Minglei
Wang, Daqi
author_facet Quan, Li
Yin, Handong
Cui, Liansheng
Yang, Minglei
Wang, Daqi
author_sort Quan, Li
collection PubMed
description The title complex, [Sb(C(6)H(5))(3)(C(8)H(4)F(3)O(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The environment of the Sb atom approximates a trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry-related 4-(trifluoro­meth­yl)benzoate ligands. In this ligand, the CF(3) group is disordered by rotation about the C—C bond and the F atoms are distributed over two sets of sites with occupancies of 0.62 (3) and 0.38 (3). In the crystal, mol­ecules are assembled in a three-dimensional framework through weak C—H⋯O hydrogen bonds.
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spelling pubmed-29695302010-12-30 Triphenyl­bis[4-(trifluoro­meth­yl)benzoato-κO]anti­mony(V) Quan, Li Yin, Handong Cui, Liansheng Yang, Minglei Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Sb(C(6)H(5))(3)(C(8)H(4)F(3)O(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The environment of the Sb atom approximates a trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry-related 4-(trifluoro­meth­yl)benzoate ligands. In this ligand, the CF(3) group is disordered by rotation about the C—C bond and the F atoms are distributed over two sets of sites with occupancies of 0.62 (3) and 0.38 (3). In the crystal, mol­ecules are assembled in a three-dimensional framework through weak C—H⋯O hydrogen bonds. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969530/ /pubmed/21583020 http://dx.doi.org/10.1107/S1600536809017449 Text en © Quan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Quan, Li
Yin, Handong
Cui, Liansheng
Yang, Minglei
Wang, Daqi
Triphenyl­bis[4-(trifluoro­meth­yl)benzoato-κO]anti­mony(V)
title Triphenyl­bis[4-(trifluoro­meth­yl)benzoato-κO]anti­mony(V)
title_full Triphenyl­bis[4-(trifluoro­meth­yl)benzoato-κO]anti­mony(V)
title_fullStr Triphenyl­bis[4-(trifluoro­meth­yl)benzoato-κO]anti­mony(V)
title_full_unstemmed Triphenyl­bis[4-(trifluoro­meth­yl)benzoato-κO]anti­mony(V)
title_short Triphenyl­bis[4-(trifluoro­meth­yl)benzoato-κO]anti­mony(V)
title_sort triphenyl­bis[4-(trifluoro­meth­yl)benzoato-κo]anti­mony(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969530/
https://www.ncbi.nlm.nih.gov/pubmed/21583020
http://dx.doi.org/10.1107/S1600536809017449
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