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catena-Poly[[diaqua(1,10-phenanthroline-κ(2) N,N′)nickel(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2) N (3):O (6)]
In the title complex, [Ni(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is hexacoordinated by one N and one O atom from two different 1H-benzimidazole-5,6-dicarboxylate ligands, two N atoms from one 1,10-phenanthroline ligand and two water molecules. The flexible 1H-benzimidazol...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969534/ https://www.ncbi.nlm.nih.gov/pubmed/21583055 http://dx.doi.org/10.1107/S1600536809019680 |
| _version_ | 1782190180472455168 |
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| author | Song, Wen-Dong Wang, Hao Hu, Shi-Wei Qin, Pei-Wen Li, Shi-Jie |
| author_facet | Song, Wen-Dong Wang, Hao Hu, Shi-Wei Qin, Pei-Wen Li, Shi-Jie |
| author_sort | Song, Wen-Dong |
| collection | PubMed |
| description | In the title complex, [Ni(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is hexacoordinated by one N and one O atom from two different 1H-benzimidazole-5,6-dicarboxylate ligands, two N atoms from one 1,10-phenanthroline ligand and two water molecules. The flexible 1H-benzimidazole-5,6-dicarboxylate ligands link the Ni(II) centres, forming an infinite zigzag chain parallel to [001]. The crystal packing is governed by intermolecular hydrogen-bonding interactions of the O—H⋯O, N—H⋯O and C—H⋯O types. |
| format | Text |
| id | pubmed-2969534 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29695342010-12-30 catena-Poly[[diaqua(1,10-phenanthroline-κ(2) N,N′)nickel(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2) N (3):O (6)] Song, Wen-Dong Wang, Hao Hu, Shi-Wei Qin, Pei-Wen Li, Shi-Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is hexacoordinated by one N and one O atom from two different 1H-benzimidazole-5,6-dicarboxylate ligands, two N atoms from one 1,10-phenanthroline ligand and two water molecules. The flexible 1H-benzimidazole-5,6-dicarboxylate ligands link the Ni(II) centres, forming an infinite zigzag chain parallel to [001]. The crystal packing is governed by intermolecular hydrogen-bonding interactions of the O—H⋯O, N—H⋯O and C—H⋯O types. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969534/ /pubmed/21583055 http://dx.doi.org/10.1107/S1600536809019680 Text en © Song et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Song, Wen-Dong Wang, Hao Hu, Shi-Wei Qin, Pei-Wen Li, Shi-Jie catena-Poly[[diaqua(1,10-phenanthroline-κ(2) N,N′)nickel(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2) N (3):O (6)] |
| title |
catena-Poly[[diaqua(1,10-phenanthroline-κ(2)
N,N′)nickel(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2)
N
(3):O
(6)] |
| title_full |
catena-Poly[[diaqua(1,10-phenanthroline-κ(2)
N,N′)nickel(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2)
N
(3):O
(6)] |
| title_fullStr |
catena-Poly[[diaqua(1,10-phenanthroline-κ(2)
N,N′)nickel(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2)
N
(3):O
(6)] |
| title_full_unstemmed |
catena-Poly[[diaqua(1,10-phenanthroline-κ(2)
N,N′)nickel(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2)
N
(3):O
(6)] |
| title_short |
catena-Poly[[diaqua(1,10-phenanthroline-κ(2)
N,N′)nickel(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2)
N
(3):O
(6)] |
| title_sort | catena-poly[[diaqua(1,10-phenanthroline-κ(2)
n,n′)nickel(ii)]-μ-1h-benzimidazole-5,6-dicarboxylato-κ(2)
n
(3):o
(6)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969534/ https://www.ncbi.nlm.nih.gov/pubmed/21583055 http://dx.doi.org/10.1107/S1600536809019680 |
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