Cargando…
4,4′-(Anthracene-9,10-diyl)dibenzoic acid dimethylformamide disolvate
In the title compound, C(28)H(18)O(4)·2C(3)H(7)NO, the dihedral angle between the benzene rings and the anthracene system is 74.05 (12)°. A crystallographic inversion centre is located in the middle of the anthracene unit. The dimethylformamide solvent molecules are partially disordered over two p...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969536/ https://www.ncbi.nlm.nih.gov/pubmed/21583091 http://dx.doi.org/10.1107/S1600536809014858 |
_version_ | 1782190181257838592 |
---|---|
author | Li, Hong Wang, Zhi-Qiang Yang, Liu-Zhi Liu, Yan-Qi Mao, Duo-Bin |
author_facet | Li, Hong Wang, Zhi-Qiang Yang, Liu-Zhi Liu, Yan-Qi Mao, Duo-Bin |
author_sort | Li, Hong |
collection | PubMed |
description | In the title compound, C(28)H(18)O(4)·2C(3)H(7)NO, the dihedral angle between the benzene rings and the anthracene system is 74.05 (12)°. A crystallographic inversion centre is located in the middle of the anthracene unit. The dimethylformamide solvent molecules are partially disordered over two positions of approximately equal occupancy [0.529 (6):0.471 (6)]. Intermolecular O—H⋯O hydrogen bonds with the major occupancy formamide O atom as acceptor result in the formation of 2:1 solvate–complex aggregates, which are alternately linked to shorter solvate units via weak intermolecular C—H⋯O contacts generated from the rotational disorder of the formamide O atom (minor occupancy component). Weak C—H⋯π interactions between the solvent molecules as the donor and the outer anthracene rings support these contacts in the crystal structure for both disorder components. |
format | Text |
id | pubmed-2969536 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29695362010-12-30 4,4′-(Anthracene-9,10-diyl)dibenzoic acid dimethylformamide disolvate Li, Hong Wang, Zhi-Qiang Yang, Liu-Zhi Liu, Yan-Qi Mao, Duo-Bin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(18)O(4)·2C(3)H(7)NO, the dihedral angle between the benzene rings and the anthracene system is 74.05 (12)°. A crystallographic inversion centre is located in the middle of the anthracene unit. The dimethylformamide solvent molecules are partially disordered over two positions of approximately equal occupancy [0.529 (6):0.471 (6)]. Intermolecular O—H⋯O hydrogen bonds with the major occupancy formamide O atom as acceptor result in the formation of 2:1 solvate–complex aggregates, which are alternately linked to shorter solvate units via weak intermolecular C—H⋯O contacts generated from the rotational disorder of the formamide O atom (minor occupancy component). Weak C—H⋯π interactions between the solvent molecules as the donor and the outer anthracene rings support these contacts in the crystal structure for both disorder components. International Union of Crystallography 2009-05-07 /pmc/articles/PMC2969536/ /pubmed/21583091 http://dx.doi.org/10.1107/S1600536809014858 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Hong Wang, Zhi-Qiang Yang, Liu-Zhi Liu, Yan-Qi Mao, Duo-Bin 4,4′-(Anthracene-9,10-diyl)dibenzoic acid dimethylformamide disolvate |
title | 4,4′-(Anthracene-9,10-diyl)dibenzoic acid dimethylformamide disolvate |
title_full | 4,4′-(Anthracene-9,10-diyl)dibenzoic acid dimethylformamide disolvate |
title_fullStr | 4,4′-(Anthracene-9,10-diyl)dibenzoic acid dimethylformamide disolvate |
title_full_unstemmed | 4,4′-(Anthracene-9,10-diyl)dibenzoic acid dimethylformamide disolvate |
title_short | 4,4′-(Anthracene-9,10-diyl)dibenzoic acid dimethylformamide disolvate |
title_sort | 4,4′-(anthracene-9,10-diyl)dibenzoic acid dimethylformamide disolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969536/ https://www.ncbi.nlm.nih.gov/pubmed/21583091 http://dx.doi.org/10.1107/S1600536809014858 |
work_keys_str_mv | AT lihong 44anthracene910diyldibenzoicaciddimethylformamidedisolvate AT wangzhiqiang 44anthracene910diyldibenzoicaciddimethylformamidedisolvate AT yangliuzhi 44anthracene910diyldibenzoicaciddimethylformamidedisolvate AT liuyanqi 44anthracene910diyldibenzoicaciddimethylformamidedisolvate AT maoduobin 44anthracene910diyldibenzoicaciddimethylformamidedisolvate |