Bis[tris(3-tert-butyl-5-methyl­pyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate

In the title compound, [Yb(C(24)H(40)BN(6))(2)]·C(7)H(8), the Yb atom is coordinated by two tris(3-tert-butyl-5-methyl­pyrazol-1-yl)hydridoborate [Tp(tBu,Me)] ligands. One ligand binds in the κ(3) mode, throuh three N atoms of the pyrazolyl rings, the other ligand coordinates through two N atoms of...

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Detalles Bibliográficos
Autores principales: Saliu, Kuburat O., Takats, Josef, Ferguson, Michael J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969540/
https://www.ncbi.nlm.nih.gov/pubmed/21583010
http://dx.doi.org/10.1107/S1600536809017152
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author Saliu, Kuburat O.
Takats, Josef
Ferguson, Michael J.
author_facet Saliu, Kuburat O.
Takats, Josef
Ferguson, Michael J.
author_sort Saliu, Kuburat O.
collection PubMed
description In the title compound, [Yb(C(24)H(40)BN(6))(2)]·C(7)H(8), the Yb atom is coordinated by two tris(3-tert-butyl-5-methyl­pyrazol-1-yl)hydridoborate [Tp(tBu,Me)] ligands. One ligand binds in the κ(3) mode, throuh three N atoms of the pyrazolyl rings, the other ligand coordinates through two N atoms of the pyrazolyl rings and the H atom attached to the central B via an agostic-type inter­action through the B—H group of the second Tp(tBu,Me) ligand, giving an overall distorted octa­hedral geometry. One of the tert-butyl groups is disordered over two sites, with occupancies of 0.65 and 0.35.
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spelling pubmed-29695402010-12-30 Bis[tris(3-tert-butyl-5-methyl­pyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate Saliu, Kuburat O. Takats, Josef Ferguson, Michael J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Yb(C(24)H(40)BN(6))(2)]·C(7)H(8), the Yb atom is coordinated by two tris(3-tert-butyl-5-methyl­pyrazol-1-yl)hydridoborate [Tp(tBu,Me)] ligands. One ligand binds in the κ(3) mode, throuh three N atoms of the pyrazolyl rings, the other ligand coordinates through two N atoms of the pyrazolyl rings and the H atom attached to the central B via an agostic-type inter­action through the B—H group of the second Tp(tBu,Me) ligand, giving an overall distorted octa­hedral geometry. One of the tert-butyl groups is disordered over two sites, with occupancies of 0.65 and 0.35. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969540/ /pubmed/21583010 http://dx.doi.org/10.1107/S1600536809017152 Text en © Saliu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Saliu, Kuburat O.
Takats, Josef
Ferguson, Michael J.
Bis[tris(3-tert-butyl-5-methyl­pyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate
title Bis[tris(3-tert-butyl-5-methyl­pyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate
title_full Bis[tris(3-tert-butyl-5-methyl­pyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate
title_fullStr Bis[tris(3-tert-butyl-5-methyl­pyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate
title_full_unstemmed Bis[tris(3-tert-butyl-5-methyl­pyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate
title_short Bis[tris(3-tert-butyl-5-methyl­pyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate
title_sort bis[tris(3-tert-butyl-5-methyl­pyrazol-1-yl)hydridoborato]ytterbium(ii) toluene solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969540/
https://www.ncbi.nlm.nih.gov/pubmed/21583010
http://dx.doi.org/10.1107/S1600536809017152
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AT takatsjosef bistris3tertbutyl5methylpyrazol1ylhydridoboratoytterbiumiitoluenesolvate
AT fergusonmichaelj bistris3tertbutyl5methylpyrazol1ylhydridoboratoytterbiumiitoluenesolvate

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