Methyl 2-[(E)-3-hydr­oxy-4-methoxy­benzyl­idene]hydrazinecarboxyl­ate

The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N bond. The hydrazinecarboxyl­ate group is twisted from the benzene ring by 6.62 (5)° and an intramolecular O—H⋯O hydrogen bond occurs. In the crystal structure, mol­ecules are linked into a two-dimensional ne...

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Detalles Bibliográficos
Autores principales: Lv, Lu-Ping, Yu, Tie-Ming, Yu, Wen-Bo, Li, Wei-Wei, Hu, Xian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969549/
https://www.ncbi.nlm.nih.gov/pubmed/21583232
http://dx.doi.org/10.1107/S1600536809018996
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author Lv, Lu-Ping
Yu, Tie-Ming
Yu, Wen-Bo
Li, Wei-Wei
Hu, Xian-Chao
author_facet Lv, Lu-Ping
Yu, Tie-Ming
Yu, Wen-Bo
Li, Wei-Wei
Hu, Xian-Chao
author_sort Lv, Lu-Ping
collection PubMed
description The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N bond. The hydrazinecarboxyl­ate group is twisted from the benzene ring by 6.62 (5)° and an intramolecular O—H⋯O hydrogen bond occurs. In the crystal structure, mol­ecules are linked into a two-dimensional network parallel to (100) by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds. In addition, weak C—H⋯π inter­actions are observed.
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spelling pubmed-29695492010-12-30 Methyl 2-[(E)-3-hydr­oxy-4-methoxy­benzyl­idene]hydrazinecarboxyl­ate Lv, Lu-Ping Yu, Tie-Ming Yu, Wen-Bo Li, Wei-Wei Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N bond. The hydrazinecarboxyl­ate group is twisted from the benzene ring by 6.62 (5)° and an intramolecular O—H⋯O hydrogen bond occurs. In the crystal structure, mol­ecules are linked into a two-dimensional network parallel to (100) by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds. In addition, weak C—H⋯π inter­actions are observed. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969549/ /pubmed/21583232 http://dx.doi.org/10.1107/S1600536809018996 Text en © Lv et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lv, Lu-Ping
Yu, Tie-Ming
Yu, Wen-Bo
Li, Wei-Wei
Hu, Xian-Chao
Methyl 2-[(E)-3-hydr­oxy-4-methoxy­benzyl­idene]hydrazinecarboxyl­ate
title Methyl 2-[(E)-3-hydr­oxy-4-methoxy­benzyl­idene]hydrazinecarboxyl­ate
title_full Methyl 2-[(E)-3-hydr­oxy-4-methoxy­benzyl­idene]hydrazinecarboxyl­ate
title_fullStr Methyl 2-[(E)-3-hydr­oxy-4-methoxy­benzyl­idene]hydrazinecarboxyl­ate
title_full_unstemmed Methyl 2-[(E)-3-hydr­oxy-4-methoxy­benzyl­idene]hydrazinecarboxyl­ate
title_short Methyl 2-[(E)-3-hydr­oxy-4-methoxy­benzyl­idene]hydrazinecarboxyl­ate
title_sort methyl 2-[(e)-3-hydr­oxy-4-methoxy­benzyl­idene]hydrazinecarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969549/
https://www.ncbi.nlm.nih.gov/pubmed/21583232
http://dx.doi.org/10.1107/S1600536809018996
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AT yuwenbo methyl2e3hydroxy4methoxybenzylidenehydrazinecarboxylate
AT liweiwei methyl2e3hydroxy4methoxybenzylidenehydrazinecarboxylate
AT huxianchao methyl2e3hydroxy4methoxybenzylidenehydrazinecarboxylate

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