Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyl­oxy­methyl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]zinc(II)]

In the title compound, [Zn(C(11)H(8)N(5)O)(N(3))](n), the Zn atom is hexa­coordinated by five N atoms and one O atom in a distorted octa­hedral geometry. The chelating 5-(8-quinolyloxymeth­yl)tetra­zolate ligands are approximately planar, with a dihedral angle of 3.6 (2)° between the quinoline and t...

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Detalles Bibliográficos
Autor principal: Cai, Hong-ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969550/
https://www.ncbi.nlm.nih.gov/pubmed/21583000
http://dx.doi.org/10.1107/S1600536809016924
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author Cai, Hong-ling
author_facet Cai, Hong-ling
author_sort Cai, Hong-ling
collection PubMed
description In the title compound, [Zn(C(11)H(8)N(5)O)(N(3))](n), the Zn atom is hexa­coordinated by five N atoms and one O atom in a distorted octa­hedral geometry. The chelating 5-(8-quinolyloxymeth­yl)tetra­zolate ligands are approximately planar, with a dihedral angle of 3.6 (2)° between the quinoline and tetra­zole planes. Adjacent Zn atoms are linked by two bridging azide ligands across a centre of inversion, and further coordination by one N atom of an adjacent tetra­zole unit forms two-dimensional frameworks in (100). C—H⋯N inter­actions exist between ligands in neighbouring layers.
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spelling pubmed-29695502010-12-30 Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyl­oxy­methyl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]zinc(II)] Cai, Hong-ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(11)H(8)N(5)O)(N(3))](n), the Zn atom is hexa­coordinated by five N atoms and one O atom in a distorted octa­hedral geometry. The chelating 5-(8-quinolyloxymeth­yl)tetra­zolate ligands are approximately planar, with a dihedral angle of 3.6 (2)° between the quinoline and tetra­zole planes. Adjacent Zn atoms are linked by two bridging azide ligands across a centre of inversion, and further coordination by one N atom of an adjacent tetra­zole unit forms two-dimensional frameworks in (100). C—H⋯N inter­actions exist between ligands in neighbouring layers. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969550/ /pubmed/21583000 http://dx.doi.org/10.1107/S1600536809016924 Text en © Hong-ling Cai 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cai, Hong-ling
Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyl­oxy­methyl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]zinc(II)]
title Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyl­oxy­methyl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]zinc(II)]
title_full Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyl­oxy­methyl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]zinc(II)]
title_fullStr Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyl­oxy­methyl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]zinc(II)]
title_full_unstemmed Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyl­oxy­methyl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]zinc(II)]
title_short Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyl­oxy­methyl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]zinc(II)]
title_sort poly[(μ(2)-azido-κ(2) n (1):n (1))[μ(2)-5-(8-quinolyl­oxy­methyl)tetra­zolato-κ(4) n (1),o,n (5):n (4)]zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969550/
https://www.ncbi.nlm.nih.gov/pubmed/21583000
http://dx.doi.org/10.1107/S1600536809016924
work_keys_str_mv AT caihongling polym2azidok2n1n1m258quinolyloxymethyltetrazolatok4n1on5n4zincii

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