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Bis[1,3(η(3))-allyl][μ-2(η(4))-1,3-bis(diphenylphosphino)-2,4-diphenylcyclobuta-1,3-diene-1:3κ(2) P:P′]dichlorido-1κCl,3κCl-[2(η(5))-isopropylcyclopentadienyl]-2-cobalt(I)-1,3-dipalladium(II) dichloromethane solvate
In the title complex, [CoPd(2)(C(3)H(5))(2)(C(8)H(11))Cl(2)(C(40)H(30)P(2))]·CH(2)Cl(2), the Co(I) atom is sandwiched between the cyclopentadienyl and cyclobutadiene rings. The two diphenylphosphine substituents of the cyclobutadiene ring are situated opposite to each other and bind two Pd(II)...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969551/ https://www.ncbi.nlm.nih.gov/pubmed/21583030 http://dx.doi.org/10.1107/S1600536809018133 |
Sumario: | In the title complex, [CoPd(2)(C(3)H(5))(2)(C(8)H(11))Cl(2)(C(40)H(30)P(2))]·CH(2)Cl(2), the Co(I) atom is sandwiched between the cyclopentadienyl and cyclobutadiene rings. The two diphenylphosphine substituents of the cyclobutadiene ring are situated opposite to each other and bind two Pd(II) atoms, which are additionally coordinated by a chloride ion and the three C atoms of an allyl ligand, forming a distorted planar coordination environment. The Cl atoms of the dichloromethane solvent molecule (equal occupancies) and one C atom and its attached H atom of each of the allyl ligands (occupancies 0.55:0.45) are disordered. |
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