Bis[1,3(η(3))-all­yl][μ-2(η(4))-1,3-bis­(di­phenyl­phosphino)-2,4-diphenyl­cyclo­buta-1,3-diene-1:3κ(2) P:P′]dichlorido-1κCl,3κCl-[2(η(5))-isopropyl­cyclo­penta­dien­yl]-2-cobalt(I)-1,3-dipalladium(II) dichloro­methane solvate

In the title complex, [CoPd(2)(C(3)H(5))(2)(C(8)H(11))Cl(2)(C(40)H(30)P(2))]·CH(2)Cl(2), the Co(I) atom is sandwiched between the cyclo­penta­dienyl and cyclo­butadiene rings. The two diphenyl­phosphine substituents of the cyclo­butadiene ring are situated opposite to each other and bind two Pd(II)...

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Detalles Bibliográficos
Autores principales: Chang, Chin-Pei, Hong, Fung-E
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969551/
https://www.ncbi.nlm.nih.gov/pubmed/21583030
http://dx.doi.org/10.1107/S1600536809018133
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author Chang, Chin-Pei
Hong, Fung-E
author_facet Chang, Chin-Pei
Hong, Fung-E
author_sort Chang, Chin-Pei
collection PubMed
description In the title complex, [CoPd(2)(C(3)H(5))(2)(C(8)H(11))Cl(2)(C(40)H(30)P(2))]·CH(2)Cl(2), the Co(I) atom is sandwiched between the cyclo­penta­dienyl and cyclo­butadiene rings. The two diphenyl­phosphine substituents of the cyclo­butadiene ring are situated opposite to each other and bind two Pd(II) atoms, which are additionally coordinated by a chloride ion and the three C atoms of an allyl ligand, forming a distorted planar coordination environment. The Cl atoms of the dichloro­methane solvent mol­ecule (equal occupancies) and one C atom and its attached H atom of each of the allyl ligands (occupancies 0.55:0.45) are disordered.
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spelling pubmed-29695512010-12-30 Bis[1,3(η(3))-all­yl][μ-2(η(4))-1,3-bis­(di­phenyl­phosphino)-2,4-diphenyl­cyclo­buta-1,3-diene-1:3κ(2) P:P′]dichlorido-1κCl,3κCl-[2(η(5))-isopropyl­cyclo­penta­dien­yl]-2-cobalt(I)-1,3-dipalladium(II) dichloro­methane solvate Chang, Chin-Pei Hong, Fung-E Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CoPd(2)(C(3)H(5))(2)(C(8)H(11))Cl(2)(C(40)H(30)P(2))]·CH(2)Cl(2), the Co(I) atom is sandwiched between the cyclo­penta­dienyl and cyclo­butadiene rings. The two diphenyl­phosphine substituents of the cyclo­butadiene ring are situated opposite to each other and bind two Pd(II) atoms, which are additionally coordinated by a chloride ion and the three C atoms of an allyl ligand, forming a distorted planar coordination environment. The Cl atoms of the dichloro­methane solvent mol­ecule (equal occupancies) and one C atom and its attached H atom of each of the allyl ligands (occupancies 0.55:0.45) are disordered. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969551/ /pubmed/21583030 http://dx.doi.org/10.1107/S1600536809018133 Text en © Chang and Hong 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chang, Chin-Pei
Hong, Fung-E
Bis[1,3(η(3))-all­yl][μ-2(η(4))-1,3-bis­(di­phenyl­phosphino)-2,4-diphenyl­cyclo­buta-1,3-diene-1:3κ(2) P:P′]dichlorido-1κCl,3κCl-[2(η(5))-isopropyl­cyclo­penta­dien­yl]-2-cobalt(I)-1,3-dipalladium(II) dichloro­methane solvate
title Bis[1,3(η(3))-all­yl][μ-2(η(4))-1,3-bis­(di­phenyl­phosphino)-2,4-diphenyl­cyclo­buta-1,3-diene-1:3κ(2) P:P′]dichlorido-1κCl,3κCl-[2(η(5))-isopropyl­cyclo­penta­dien­yl]-2-cobalt(I)-1,3-dipalladium(II) dichloro­methane solvate
title_full Bis[1,3(η(3))-all­yl][μ-2(η(4))-1,3-bis­(di­phenyl­phosphino)-2,4-diphenyl­cyclo­buta-1,3-diene-1:3κ(2) P:P′]dichlorido-1κCl,3κCl-[2(η(5))-isopropyl­cyclo­penta­dien­yl]-2-cobalt(I)-1,3-dipalladium(II) dichloro­methane solvate
title_fullStr Bis[1,3(η(3))-all­yl][μ-2(η(4))-1,3-bis­(di­phenyl­phosphino)-2,4-diphenyl­cyclo­buta-1,3-diene-1:3κ(2) P:P′]dichlorido-1κCl,3κCl-[2(η(5))-isopropyl­cyclo­penta­dien­yl]-2-cobalt(I)-1,3-dipalladium(II) dichloro­methane solvate
title_full_unstemmed Bis[1,3(η(3))-all­yl][μ-2(η(4))-1,3-bis­(di­phenyl­phosphino)-2,4-diphenyl­cyclo­buta-1,3-diene-1:3κ(2) P:P′]dichlorido-1κCl,3κCl-[2(η(5))-isopropyl­cyclo­penta­dien­yl]-2-cobalt(I)-1,3-dipalladium(II) dichloro­methane solvate
title_short Bis[1,3(η(3))-all­yl][μ-2(η(4))-1,3-bis­(di­phenyl­phosphino)-2,4-diphenyl­cyclo­buta-1,3-diene-1:3κ(2) P:P′]dichlorido-1κCl,3κCl-[2(η(5))-isopropyl­cyclo­penta­dien­yl]-2-cobalt(I)-1,3-dipalladium(II) dichloro­methane solvate
title_sort bis[1,3(η(3))-all­yl][μ-2(η(4))-1,3-bis­(di­phenyl­phosphino)-2,4-diphenyl­cyclo­buta-1,3-diene-1:3κ(2) p:p′]dichlorido-1κcl,3κcl-[2(η(5))-isopropyl­cyclo­penta­dien­yl]-2-cobalt(i)-1,3-dipalladium(ii) dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969551/
https://www.ncbi.nlm.nih.gov/pubmed/21583030
http://dx.doi.org/10.1107/S1600536809018133
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AT hongfunge bis13ē3allylm2ē413bisdiphenylphosphino24diphenylcyclobuta13diene13k2ppdichlorido1kcl3kcl2ē5isopropylcyclopentadienyl2cobalti13dipalladiumiidichloromethanesolvate

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