Methyl 4-anilino-3-nitro­benzoate

In the mol­ecule of the title compound, C(14)H(12)N(2)O(4), the aromatic rings are oriented at a dihedral angle of 51.50 (4)°. An intra­molecular N—H⋯O inter­action results in the formation of a six-membered ring having an envelope conformation. In the crystal structure, inter­molecular N—H⋯O inter­...

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Autores principales: Li, Hao-Yuan, Wu, Yong-Zhong, Liu, Bo-Nian, Tang, Shi-Gui, Guo, Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969563/
https://www.ncbi.nlm.nih.gov/pubmed/21583229
http://dx.doi.org/10.1107/S1600536809018923
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author Li, Hao-Yuan
Wu, Yong-Zhong
Liu, Bo-Nian
Tang, Shi-Gui
Guo, Cheng
author_facet Li, Hao-Yuan
Wu, Yong-Zhong
Liu, Bo-Nian
Tang, Shi-Gui
Guo, Cheng
author_sort Li, Hao-Yuan
collection PubMed
description In the mol­ecule of the title compound, C(14)H(12)N(2)O(4), the aromatic rings are oriented at a dihedral angle of 51.50 (4)°. An intra­molecular N—H⋯O inter­action results in the formation of a six-membered ring having an envelope conformation. In the crystal structure, inter­molecular N—H⋯O inter­actions link the mol­ecules into centrosymmetric dimers. π–π contacts between the benzene rings [centroid–centroid distance = 3.708 (1) Å] may further stabilize the structure.
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spelling pubmed-29695632010-12-30 Methyl 4-anilino-3-nitro­benzoate Li, Hao-Yuan Wu, Yong-Zhong Liu, Bo-Nian Tang, Shi-Gui Guo, Cheng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(14)H(12)N(2)O(4), the aromatic rings are oriented at a dihedral angle of 51.50 (4)°. An intra­molecular N—H⋯O inter­action results in the formation of a six-membered ring having an envelope conformation. In the crystal structure, inter­molecular N—H⋯O inter­actions link the mol­ecules into centrosymmetric dimers. π–π contacts between the benzene rings [centroid–centroid distance = 3.708 (1) Å] may further stabilize the structure. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969563/ /pubmed/21583229 http://dx.doi.org/10.1107/S1600536809018923 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Hao-Yuan
Wu, Yong-Zhong
Liu, Bo-Nian
Tang, Shi-Gui
Guo, Cheng
Methyl 4-anilino-3-nitro­benzoate
title Methyl 4-anilino-3-nitro­benzoate
title_full Methyl 4-anilino-3-nitro­benzoate
title_fullStr Methyl 4-anilino-3-nitro­benzoate
title_full_unstemmed Methyl 4-anilino-3-nitro­benzoate
title_short Methyl 4-anilino-3-nitro­benzoate
title_sort methyl 4-anilino-3-nitro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969563/
https://www.ncbi.nlm.nih.gov/pubmed/21583229
http://dx.doi.org/10.1107/S1600536809018923
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AT guocheng methyl4anilino3nitrobenzoate

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