Dibromido(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)

In the title compound, [ZnBr(2)(C(15)H(11)N(3))], the Zn(II) ion is five-coordinated by the three N atoms from a 2,2′:6′,2′′-terpyridine ligand (terpy) and two bromide anions in a distorted trigonal bipyramidal configuration. Each mol­ecule is situated on a twofold rotational axis that passes throug...

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Detalles Bibliográficos
Autores principales: Zhao, Qing-Lan, Li, Guo-Peng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969570/
https://www.ncbi.nlm.nih.gov/pubmed/21583049
http://dx.doi.org/10.1107/S1600536809019266
Descripción
Sumario:In the title compound, [ZnBr(2)(C(15)H(11)N(3))], the Zn(II) ion is five-coordinated by the three N atoms from a 2,2′:6′,2′′-terpyridine ligand (terpy) and two bromide anions in a distorted trigonal bipyramidal configuration. Each mol­ecule is situated on a twofold rotational axis that passes through the Zn(II) ion and the central ring of the terpy ligand. In the crystal structure, aromatic π–π inter­actions between terpy ligands [centroid–centroid distances = 3.6265 (9) Å] link mol­ecules into stacks propagated in the [001] direction.

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