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Dibromido(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)
In the title compound, [ZnBr(2)(C(15)H(11)N(3))], the Zn(II) ion is five-coordinated by the three N atoms from a 2,2′:6′,2′′-terpyridine ligand (terpy) and two bromide anions in a distorted trigonal bipyramidal configuration. Each molecule is situated on a twofold rotational axis that passes throug...
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969570/ https://www.ncbi.nlm.nih.gov/pubmed/21583049 http://dx.doi.org/10.1107/S1600536809019266 |
| _version_ | 1782190190978138112 |
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| author | Zhao, Qing-Lan Li, Guo-Peng |
| author_facet | Zhao, Qing-Lan Li, Guo-Peng |
| author_sort | Zhao, Qing-Lan |
| collection | PubMed |
| description | In the title compound, [ZnBr(2)(C(15)H(11)N(3))], the Zn(II) ion is five-coordinated by the three N atoms from a 2,2′:6′,2′′-terpyridine ligand (terpy) and two bromide anions in a distorted trigonal bipyramidal configuration. Each molecule is situated on a twofold rotational axis that passes through the Zn(II) ion and the central ring of the terpy ligand. In the crystal structure, aromatic π–π interactions between terpy ligands [centroid–centroid distances = 3.6265 (9) Å] link molecules into stacks propagated in the [001] direction. |
| format | Text |
| id | pubmed-2969570 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29695702010-12-30 Dibromido(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II) Zhao, Qing-Lan Li, Guo-Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnBr(2)(C(15)H(11)N(3))], the Zn(II) ion is five-coordinated by the three N atoms from a 2,2′:6′,2′′-terpyridine ligand (terpy) and two bromide anions in a distorted trigonal bipyramidal configuration. Each molecule is situated on a twofold rotational axis that passes through the Zn(II) ion and the central ring of the terpy ligand. In the crystal structure, aromatic π–π interactions between terpy ligands [centroid–centroid distances = 3.6265 (9) Å] link molecules into stacks propagated in the [001] direction. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969570/ /pubmed/21583049 http://dx.doi.org/10.1107/S1600536809019266 Text en © Zhao and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhao, Qing-Lan Li, Guo-Peng Dibromido(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II) |
| title | Dibromido(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)zinc(II) |
| title_full | Dibromido(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)zinc(II) |
| title_fullStr | Dibromido(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)zinc(II) |
| title_full_unstemmed | Dibromido(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)zinc(II) |
| title_short | Dibromido(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)zinc(II) |
| title_sort | dibromido(2,2′:6′,2′′-terpyridine-κ(3)
n,n′,n′′)zinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969570/ https://www.ncbi.nlm.nih.gov/pubmed/21583049 http://dx.doi.org/10.1107/S1600536809019266 |
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