(η(5)-Cyclo­penta­dien­yl)(η(6)-mesitylamine)ruthenium(II) hexa­fluorido­phosphate

The title compound, [Ru(η(5)-C(5)H(5)){η(6)-C(6)H(2)(CH(3))(3)NH(2)}]PF(6), contains a sandwich complex with a mesitylamine unit which is significantly non-planar at the ipso-carbon of the amino group due to repulsive electronic effects with Ru. The ipso-carbon deviates by 0.107 (3) Å from the least...

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Detalles Bibliográficos
Autores principales: Becker, Eva, Kirchner, Karl, Mereiter, Kurt
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969571/
https://www.ncbi.nlm.nih.gov/pubmed/21582999
http://dx.doi.org/10.1107/S1600536809016894
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author Becker, Eva
Kirchner, Karl
Mereiter, Kurt
author_facet Becker, Eva
Kirchner, Karl
Mereiter, Kurt
author_sort Becker, Eva
collection PubMed
description The title compound, [Ru(η(5)-C(5)H(5)){η(6)-C(6)H(2)(CH(3))(3)NH(2)}]PF(6), contains a sandwich complex with a mesitylamine unit which is significantly non-planar at the ipso-carbon of the amino group due to repulsive electronic effects with Ru. The ipso-carbon deviates by 0.107 (3) Å from the least-squares plane of the remaining five benzene ring atoms, which show an r.m.s. deviation of 0.005 Å. N—H⋯F hydrogen-bonding interactions help to consolidate the crystal packing.
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spelling pubmed-29695712010-12-30 (η(5)-Cyclo­penta­dien­yl)(η(6)-mesitylamine)ruthenium(II) hexa­fluorido­phosphate Becker, Eva Kirchner, Karl Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ru(η(5)-C(5)H(5)){η(6)-C(6)H(2)(CH(3))(3)NH(2)}]PF(6), contains a sandwich complex with a mesitylamine unit which is significantly non-planar at the ipso-carbon of the amino group due to repulsive electronic effects with Ru. The ipso-carbon deviates by 0.107 (3) Å from the least-squares plane of the remaining five benzene ring atoms, which show an r.m.s. deviation of 0.005 Å. N—H⋯F hydrogen-bonding interactions help to consolidate the crystal packing. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969571/ /pubmed/21582999 http://dx.doi.org/10.1107/S1600536809016894 Text en © Becker et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Becker, Eva
Kirchner, Karl
Mereiter, Kurt
(η(5)-Cyclo­penta­dien­yl)(η(6)-mesitylamine)ruthenium(II) hexa­fluorido­phosphate
title (η(5)-Cyclo­penta­dien­yl)(η(6)-mesitylamine)ruthenium(II) hexa­fluorido­phosphate
title_full (η(5)-Cyclo­penta­dien­yl)(η(6)-mesitylamine)ruthenium(II) hexa­fluorido­phosphate
title_fullStr (η(5)-Cyclo­penta­dien­yl)(η(6)-mesitylamine)ruthenium(II) hexa­fluorido­phosphate
title_full_unstemmed (η(5)-Cyclo­penta­dien­yl)(η(6)-mesitylamine)ruthenium(II) hexa­fluorido­phosphate
title_short (η(5)-Cyclo­penta­dien­yl)(η(6)-mesitylamine)ruthenium(II) hexa­fluorido­phosphate
title_sort (η(5)-cyclo­penta­dien­yl)(η(6)-mesitylamine)ruthenium(ii) hexa­fluorido­phosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969571/
https://www.ncbi.nlm.nih.gov/pubmed/21582999
http://dx.doi.org/10.1107/S1600536809016894
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AT mereiterkurt ē5cyclopentadienylē6mesitylaminerutheniumiihexafluoridophosphate

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