2-{4-[(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-yl­idene)methyl­amino]phen­yl}acetonitrile

The title compound, C(15)H(14)N(2)O(4), is approximately planar, with a dihedral angle of 6.48 (4)° between the amino­methyl­ene unit and the planar five-atom part of the dioxane ring, and a dihedral angle of 2.40 (4)° between amino­methyl­ene unit and the phenyl­ene ring. The dioxane ring is envelo...

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Detalles Bibliográficos
Autores principales: Li, Rui, Ding, Zhen-Yu, Wei, Yu-Quan, Ding, Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969579/
https://www.ncbi.nlm.nih.gov/pubmed/21583155
http://dx.doi.org/10.1107/S1600536809017437
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author Li, Rui
Ding, Zhen-Yu
Wei, Yu-Quan
Ding, Jian
author_facet Li, Rui
Ding, Zhen-Yu
Wei, Yu-Quan
Ding, Jian
author_sort Li, Rui
collection PubMed
description The title compound, C(15)H(14)N(2)O(4), is approximately planar, with a dihedral angle of 6.48 (4)° between the amino­methyl­ene unit and the planar five-atom part of the dioxane ring, and a dihedral angle of 2.40 (4)° between amino­methyl­ene unit and the phenyl­ene ring. The dioxane ring is envelope shaped, with the dimethyl-substituted C atom that represents the flap 0.535 (8) Å out of the plane. The mol­ecule has an intra­molecular N—H⋯O hydrogen bond.
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spelling pubmed-29695792010-12-30 2-{4-[(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-yl­idene)methyl­amino]phen­yl}acetonitrile Li, Rui Ding, Zhen-Yu Wei, Yu-Quan Ding, Jian Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(14)N(2)O(4), is approximately planar, with a dihedral angle of 6.48 (4)° between the amino­methyl­ene unit and the planar five-atom part of the dioxane ring, and a dihedral angle of 2.40 (4)° between amino­methyl­ene unit and the phenyl­ene ring. The dioxane ring is envelope shaped, with the dimethyl-substituted C atom that represents the flap 0.535 (8) Å out of the plane. The mol­ecule has an intra­molecular N—H⋯O hydrogen bond. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969579/ /pubmed/21583155 http://dx.doi.org/10.1107/S1600536809017437 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Rui
Ding, Zhen-Yu
Wei, Yu-Quan
Ding, Jian
2-{4-[(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-yl­idene)methyl­amino]phen­yl}acetonitrile
title 2-{4-[(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-yl­idene)methyl­amino]phen­yl}acetonitrile
title_full 2-{4-[(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-yl­idene)methyl­amino]phen­yl}acetonitrile
title_fullStr 2-{4-[(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-yl­idene)methyl­amino]phen­yl}acetonitrile
title_full_unstemmed 2-{4-[(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-yl­idene)methyl­amino]phen­yl}acetonitrile
title_short 2-{4-[(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-yl­idene)methyl­amino]phen­yl}acetonitrile
title_sort 2-{4-[(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl­idene)methyl­amino]phen­yl}acetonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969579/
https://www.ncbi.nlm.nih.gov/pubmed/21583155
http://dx.doi.org/10.1107/S1600536809017437
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AT weiyuquan 2422dimethyl46dioxo13dioxan5ylidenemethylaminophenylacetonitrile
AT dingjian 2422dimethyl46dioxo13dioxan5ylidenemethylaminophenylacetonitrile

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