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Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2) N (2),N (3)]copper(II) dinitrate dihydrate
In the title compound, [Cu(C(11)H(13)N(3))(2)](NO(3))(2)·2H(2)O, synthesized by hydrothermal reaction of Cu(NO(3))(2) and racemic 2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole, the Cu(II) atom lies on an inversion centre. The distorted octahedral Cu(II) environment contains two planar trans-related N,N...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969581/ https://www.ncbi.nlm.nih.gov/pubmed/21583023 http://dx.doi.org/10.1107/S160053680901808X |
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author | Dai, Jing |
author_facet | Dai, Jing |
author_sort | Dai, Jing |
collection | PubMed |
description | In the title compound, [Cu(C(11)H(13)N(3))(2)](NO(3))(2)·2H(2)O, synthesized by hydrothermal reaction of Cu(NO(3))(2) and racemic 2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole, the Cu(II) atom lies on an inversion centre. The distorted octahedral Cu(II) environment contains two planar trans-related N,N-chelating 2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole ligands in the equatorial plane and two monodentate nitrate anions, which are in weak interaction with the Cu atom, in the axial positions. The two benzimidazole ligands have opposite configurations (R/S and S/R) and compound is a meso complex. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds generate an infinite three-dimensional network. One methylene group of the pyrrolidine ring is disordered over two position with a 0.56 (3):0.44 (3) occupancy. |
format | Text |
id | pubmed-2969581 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29695812010-12-30 Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2) N (2),N (3)]copper(II) dinitrate dihydrate Dai, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(11)H(13)N(3))(2)](NO(3))(2)·2H(2)O, synthesized by hydrothermal reaction of Cu(NO(3))(2) and racemic 2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole, the Cu(II) atom lies on an inversion centre. The distorted octahedral Cu(II) environment contains two planar trans-related N,N-chelating 2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole ligands in the equatorial plane and two monodentate nitrate anions, which are in weak interaction with the Cu atom, in the axial positions. The two benzimidazole ligands have opposite configurations (R/S and S/R) and compound is a meso complex. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds generate an infinite three-dimensional network. One methylene group of the pyrrolidine ring is disordered over two position with a 0.56 (3):0.44 (3) occupancy. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969581/ /pubmed/21583023 http://dx.doi.org/10.1107/S160053680901808X Text en © Jing Dai 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Dai, Jing Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2) N (2),N (3)]copper(II) dinitrate dihydrate |
title | Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]copper(II) dinitrate dihydrate |
title_full | Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]copper(II) dinitrate dihydrate |
title_fullStr | Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]copper(II) dinitrate dihydrate |
title_full_unstemmed | Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]copper(II) dinitrate dihydrate |
title_short | Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]copper(II) dinitrate dihydrate |
title_sort | bis[2-(pyrrolidin-2-yl)-1h-benzimidazole-κ(2)
n
(2),n
(3)]copper(ii) dinitrate dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969581/ https://www.ncbi.nlm.nih.gov/pubmed/21583023 http://dx.doi.org/10.1107/S160053680901808X |
work_keys_str_mv | AT daijing bis2pyrrolidin2yl1hbenzimidazolek2n2n3copperiidinitratedihydrate |