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Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2) N (2),N (3)]copper(II) dinitrate dihydrate

In the title compound, [Cu(C(11)H(13)N(3))(2)](NO(3))(2)·2H(2)O, synthesized by hydro­thermal reaction of Cu(NO(3))(2) and racemic 2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole, the Cu(II) atom lies on an inversion centre. The distorted octa­hedral Cu(II) environment contains two planar trans-related N,N...

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Autor principal: Dai, Jing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969581/
https://www.ncbi.nlm.nih.gov/pubmed/21583023
http://dx.doi.org/10.1107/S160053680901808X
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author Dai, Jing
author_facet Dai, Jing
author_sort Dai, Jing
collection PubMed
description In the title compound, [Cu(C(11)H(13)N(3))(2)](NO(3))(2)·2H(2)O, synthesized by hydro­thermal reaction of Cu(NO(3))(2) and racemic 2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole, the Cu(II) atom lies on an inversion centre. The distorted octa­hedral Cu(II) environment contains two planar trans-related N,N-chelating 2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole ligands in the equatorial plane and two monodentate nitrate anions, which are in weak inter­action with the Cu atom, in the axial positions. The two benzimidazole ligands have opposite configurations (R/S and S/R) and compound is a meso complex. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds generate an infinite three-dimensional network. One methylene group of the pyrrolidine ring is disordered over two position with a 0.56 (3):0.44 (3) occupancy.
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spelling pubmed-29695812010-12-30 Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2) N (2),N (3)]copper(II) dinitrate dihydrate Dai, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(11)H(13)N(3))(2)](NO(3))(2)·2H(2)O, synthesized by hydro­thermal reaction of Cu(NO(3))(2) and racemic 2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole, the Cu(II) atom lies on an inversion centre. The distorted octa­hedral Cu(II) environment contains two planar trans-related N,N-chelating 2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole ligands in the equatorial plane and two monodentate nitrate anions, which are in weak inter­action with the Cu atom, in the axial positions. The two benzimidazole ligands have opposite configurations (R/S and S/R) and compound is a meso complex. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds generate an infinite three-dimensional network. One methylene group of the pyrrolidine ring is disordered over two position with a 0.56 (3):0.44 (3) occupancy. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969581/ /pubmed/21583023 http://dx.doi.org/10.1107/S160053680901808X Text en © Jing Dai 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dai, Jing
Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2) N (2),N (3)]copper(II) dinitrate dihydrate
title Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2) N (2),N (3)]copper(II) dinitrate dihydrate
title_full Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2) N (2),N (3)]copper(II) dinitrate dihydrate
title_fullStr Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2) N (2),N (3)]copper(II) dinitrate dihydrate
title_full_unstemmed Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2) N (2),N (3)]copper(II) dinitrate dihydrate
title_short Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ(2) N (2),N (3)]copper(II) dinitrate dihydrate
title_sort bis[2-(pyrrolidin-2-yl)-1h-benzimidazole-κ(2) n (2),n (3)]copper(ii) dinitrate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969581/
https://www.ncbi.nlm.nih.gov/pubmed/21583023
http://dx.doi.org/10.1107/S160053680901808X
work_keys_str_mv AT daijing bis2pyrrolidin2yl1hbenzimidazolek2n2n3copperiidinitratedihydrate