Cargando…

1-[2-(Benzyl­amino)-4-pyrid­yl]-2-(4-fluoro­phen­yl)ethane-1,2-dione

The crystal structure of the title compound, C(20)H(15)FN(2)O(2), contains two crystallographically independent mol­ecules, which are related by a pseudo-inversion center and linked into dimers via inter­molecular N—H⋯N hydrogen bonds. The 4-fluoro­phenyl ring of mol­ecule A makes dihedral angles of...

Descripción completa

Detalles Bibliográficos
Autores principales: Jahns, Hartmut, Koch, Pierre, Schollmeyer, Dieter, Laufer, Stefan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969582/
https://www.ncbi.nlm.nih.gov/pubmed/21583289
http://dx.doi.org/10.1107/S1600536809019801
_version_ 1782190194877792256
author Jahns, Hartmut
Koch, Pierre
Schollmeyer, Dieter
Laufer, Stefan
author_facet Jahns, Hartmut
Koch, Pierre
Schollmeyer, Dieter
Laufer, Stefan
author_sort Jahns, Hartmut
collection PubMed
description The crystal structure of the title compound, C(20)H(15)FN(2)O(2), contains two crystallographically independent mol­ecules, which are related by a pseudo-inversion center and linked into dimers via inter­molecular N—H⋯N hydrogen bonds. The 4-fluoro­phenyl ring of mol­ecule A makes dihedral angles of 17.17 (16) and 62.25 (15)°, respectively, with the phenyl and pyridine rings. The 4-fluoro­phenyl ring of mol­ecule B makes dihedral angles of 8.50 (16) and 64.59 (15)°, respectively, with the phenyl and pyridine rings. The dihedral angle between the pyridine ring and the phenyl ring of mol­ecule A [60.97 (15)°] is bigger than in mol­ecule B [59.49 (15)°]. The dihedral angle between the two pyridine rings is 1.37 (14)° and between the two phenyl rings is 3.64 (16)°.
format Text
id pubmed-2969582
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29695822010-12-30 1-[2-(Benzyl­amino)-4-pyrid­yl]-2-(4-fluoro­phen­yl)ethane-1,2-dione Jahns, Hartmut Koch, Pierre Schollmeyer, Dieter Laufer, Stefan Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(20)H(15)FN(2)O(2), contains two crystallographically independent mol­ecules, which are related by a pseudo-inversion center and linked into dimers via inter­molecular N—H⋯N hydrogen bonds. The 4-fluoro­phenyl ring of mol­ecule A makes dihedral angles of 17.17 (16) and 62.25 (15)°, respectively, with the phenyl and pyridine rings. The 4-fluoro­phenyl ring of mol­ecule B makes dihedral angles of 8.50 (16) and 64.59 (15)°, respectively, with the phenyl and pyridine rings. The dihedral angle between the pyridine ring and the phenyl ring of mol­ecule A [60.97 (15)°] is bigger than in mol­ecule B [59.49 (15)°]. The dihedral angle between the two pyridine rings is 1.37 (14)° and between the two phenyl rings is 3.64 (16)°. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969582/ /pubmed/21583289 http://dx.doi.org/10.1107/S1600536809019801 Text en © Jahns et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jahns, Hartmut
Koch, Pierre
Schollmeyer, Dieter
Laufer, Stefan
1-[2-(Benzyl­amino)-4-pyrid­yl]-2-(4-fluoro­phen­yl)ethane-1,2-dione
title 1-[2-(Benzyl­amino)-4-pyrid­yl]-2-(4-fluoro­phen­yl)ethane-1,2-dione
title_full 1-[2-(Benzyl­amino)-4-pyrid­yl]-2-(4-fluoro­phen­yl)ethane-1,2-dione
title_fullStr 1-[2-(Benzyl­amino)-4-pyrid­yl]-2-(4-fluoro­phen­yl)ethane-1,2-dione
title_full_unstemmed 1-[2-(Benzyl­amino)-4-pyrid­yl]-2-(4-fluoro­phen­yl)ethane-1,2-dione
title_short 1-[2-(Benzyl­amino)-4-pyrid­yl]-2-(4-fluoro­phen­yl)ethane-1,2-dione
title_sort 1-[2-(benzyl­amino)-4-pyrid­yl]-2-(4-fluoro­phen­yl)ethane-1,2-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969582/
https://www.ncbi.nlm.nih.gov/pubmed/21583289
http://dx.doi.org/10.1107/S1600536809019801
work_keys_str_mv AT jahnshartmut 12benzylamino4pyridyl24fluorophenylethane12dione
AT kochpierre 12benzylamino4pyridyl24fluorophenylethane12dione
AT schollmeyerdieter 12benzylamino4pyridyl24fluorophenylethane12dione
AT lauferstefan 12benzylamino4pyridyl24fluorophenylethane12dione