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N′-[(E)-4-Chloro­benzyl­idene]-2-(4-isobutyl­phen­yl)propanohydrazide

The asymmetric unit of title compound, C(20)H(23)ClN(2)O, consists of two crystallographically independent mol­ecules (A and B) in which the orientations of the 4-isobutyl­phenyl units are different. The isobutyl group of mol­ecule B is disordered over two positions with occupancies of 0.850 (5) and...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Yeap, Chin Sing, Sujith, K. V., Kalluraya, B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969596/
https://www.ncbi.nlm.nih.gov/pubmed/21583068
http://dx.doi.org/10.1107/S1600536809015906
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author Fun, Hoong-Kun
Yeap, Chin Sing
Sujith, K. V.
Kalluraya, B.
author_facet Fun, Hoong-Kun
Yeap, Chin Sing
Sujith, K. V.
Kalluraya, B.
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of title compound, C(20)H(23)ClN(2)O, consists of two crystallographically independent mol­ecules (A and B) in which the orientations of the 4-isobutyl­phenyl units are different. The isobutyl group of mol­ecule B is disordered over two positions with occupancies of 0.850 (5) and 0.150 (5). The dihedral angle between the two benzene rings is 88.70 (9)° in mol­ecule A and 89.38 (9)° in mol­ecule B. The independent mol­ecules are linked together into chains along [100] by N—H⋯O and C—H⋯O hydrogen bonds, and by C—H⋯π inter­actions. In the chain, N—H⋯O and C—H⋯O hydrogen bonds generate R (2) (1)(6) ring motifs. In addition, C—H⋯N hydrogen bonds are observed. The presence of pseudosymmetry in the structure suggests the higher symmetry space group Pbca but attempts to refine the structure in this space group resulted in high R (0.119) and wR (0.296) values.
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spelling pubmed-29695962010-12-30 N′-[(E)-4-Chloro­benzyl­idene]-2-(4-isobutyl­phen­yl)propanohydrazide Fun, Hoong-Kun Yeap, Chin Sing Sujith, K. V. Kalluraya, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of title compound, C(20)H(23)ClN(2)O, consists of two crystallographically independent mol­ecules (A and B) in which the orientations of the 4-isobutyl­phenyl units are different. The isobutyl group of mol­ecule B is disordered over two positions with occupancies of 0.850 (5) and 0.150 (5). The dihedral angle between the two benzene rings is 88.70 (9)° in mol­ecule A and 89.38 (9)° in mol­ecule B. The independent mol­ecules are linked together into chains along [100] by N—H⋯O and C—H⋯O hydrogen bonds, and by C—H⋯π inter­actions. In the chain, N—H⋯O and C—H⋯O hydrogen bonds generate R (2) (1)(6) ring motifs. In addition, C—H⋯N hydrogen bonds are observed. The presence of pseudosymmetry in the structure suggests the higher symmetry space group Pbca but attempts to refine the structure in this space group resulted in high R (0.119) and wR (0.296) values. International Union of Crystallography 2009-05-07 /pmc/articles/PMC2969596/ /pubmed/21583068 http://dx.doi.org/10.1107/S1600536809015906 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Yeap, Chin Sing
Sujith, K. V.
Kalluraya, B.
N′-[(E)-4-Chloro­benzyl­idene]-2-(4-isobutyl­phen­yl)propanohydrazide
title N′-[(E)-4-Chloro­benzyl­idene]-2-(4-isobutyl­phen­yl)propanohydrazide
title_full N′-[(E)-4-Chloro­benzyl­idene]-2-(4-isobutyl­phen­yl)propanohydrazide
title_fullStr N′-[(E)-4-Chloro­benzyl­idene]-2-(4-isobutyl­phen­yl)propanohydrazide
title_full_unstemmed N′-[(E)-4-Chloro­benzyl­idene]-2-(4-isobutyl­phen­yl)propanohydrazide
title_short N′-[(E)-4-Chloro­benzyl­idene]-2-(4-isobutyl­phen­yl)propanohydrazide
title_sort n′-[(e)-4-chloro­benzyl­idene]-2-(4-isobutyl­phen­yl)propanohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969596/
https://www.ncbi.nlm.nih.gov/pubmed/21583068
http://dx.doi.org/10.1107/S1600536809015906
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