Poly[[μ(4)-tartrato-cadmium(II)] 0.167-hydrate]

The title compound, {[Cd(C(4)H(4)O(6))]·0.167H(2)O}(n), adopts a three-dimensional network structure in which each Cd(II) ion is chelated by two pairs of carboxyl­ate and hydroxyl O atoms from two tartrate anions, and is additionally linked to two O atoms of two carboxyl­ate groups that are not invo...

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Detalles Bibliográficos
Autores principales: Zhao, Li-Zhen, Li, Ping, Cao, Bao-Liang, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969599/
https://www.ncbi.nlm.nih.gov/pubmed/21582997
http://dx.doi.org/10.1107/S1600536809016882
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author Zhao, Li-Zhen
Li, Ping
Cao, Bao-Liang
Ng, Seik Weng
author_facet Zhao, Li-Zhen
Li, Ping
Cao, Bao-Liang
Ng, Seik Weng
author_sort Zhao, Li-Zhen
collection PubMed
description The title compound, {[Cd(C(4)H(4)O(6))]·0.167H(2)O}(n), adopts a three-dimensional network structure in which each Cd(II) ion is chelated by two pairs of carboxyl­ate and hydroxyl O atoms from two tartrate anions, and is additionally linked to two O atoms of two carboxyl­ate groups that are not involved in chelation. The asymmetric unit has four independent cadmium atoms, two of which lie on special positions of 2 site symmetry. The tartrate anions all lie on general positions. All hydroxyl groups are engaged in O—H⋯O hydrogen-bonds, one of which is also bifurcated. The non-coordinating water molecule is situated on a site with half-occupation.
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spelling pubmed-29695992010-12-30 Poly[[μ(4)-tartrato-cadmium(II)] 0.167-hydrate] Zhao, Li-Zhen Li, Ping Cao, Bao-Liang Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Cd(C(4)H(4)O(6))]·0.167H(2)O}(n), adopts a three-dimensional network structure in which each Cd(II) ion is chelated by two pairs of carboxyl­ate and hydroxyl O atoms from two tartrate anions, and is additionally linked to two O atoms of two carboxyl­ate groups that are not involved in chelation. The asymmetric unit has four independent cadmium atoms, two of which lie on special positions of 2 site symmetry. The tartrate anions all lie on general positions. All hydroxyl groups are engaged in O—H⋯O hydrogen-bonds, one of which is also bifurcated. The non-coordinating water molecule is situated on a site with half-occupation. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969599/ /pubmed/21582997 http://dx.doi.org/10.1107/S1600536809016882 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Li-Zhen
Li, Ping
Cao, Bao-Liang
Ng, Seik Weng
Poly[[μ(4)-tartrato-cadmium(II)] 0.167-hydrate]
title Poly[[μ(4)-tartrato-cadmium(II)] 0.167-hydrate]
title_full Poly[[μ(4)-tartrato-cadmium(II)] 0.167-hydrate]
title_fullStr Poly[[μ(4)-tartrato-cadmium(II)] 0.167-hydrate]
title_full_unstemmed Poly[[μ(4)-tartrato-cadmium(II)] 0.167-hydrate]
title_short Poly[[μ(4)-tartrato-cadmium(II)] 0.167-hydrate]
title_sort poly[[μ(4)-tartrato-cadmium(ii)] 0.167-hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969599/
https://www.ncbi.nlm.nih.gov/pubmed/21582997
http://dx.doi.org/10.1107/S1600536809016882
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AT liping polym4tartratocadmiumii0167hydrate
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AT ngseikweng polym4tartratocadmiumii0167hydrate

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