[1-(1-Adamantylamino)ethyl­idene]oxonium methane­sulfonate

In the title salt, C(12)H(20)NO(+)·CH(3)SO(3) (−), the [1-(1-adamantyl­amino)ethyl­idene]oxonium cations and methane­sulfonate anions are linked into chains along the a axis via O—H⋯O and N—H⋯O hydrogen bonds. All non-H atoms of the acetamido group are essentially planar, with a maximum deviation of...

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Detalles Bibliográficos
Autores principales: Vícha, Robert, Nečas, Marek, Kozubková, Zuzana, Potáček, Milan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969600/
https://www.ncbi.nlm.nih.gov/pubmed/21583164
http://dx.doi.org/10.1107/S1600536809017632
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author Vícha, Robert
Nečas, Marek
Kozubková, Zuzana
Potáček, Milan
author_facet Vícha, Robert
Nečas, Marek
Kozubková, Zuzana
Potáček, Milan
author_sort Vícha, Robert
collection PubMed
description In the title salt, C(12)H(20)NO(+)·CH(3)SO(3) (−), the [1-(1-adamantyl­amino)ethyl­idene]oxonium cations and methane­sulfonate anions are linked into chains along the a axis via O—H⋯O and N—H⋯O hydrogen bonds. All non-H atoms of the acetamido group are essentially planar, with a maximum deviation of 0.0085 (12) Å. In comparison with related structures, the carbonyl C=O bond is slightly elongated [1.249 (2) Å], whereas the amide C—N bond is shortened [1.292 (2) Å].
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spelling pubmed-29696002010-12-30 [1-(1-Adamantylamino)ethyl­idene]oxonium methane­sulfonate Vícha, Robert Nečas, Marek Kozubková, Zuzana Potáček, Milan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(12)H(20)NO(+)·CH(3)SO(3) (−), the [1-(1-adamantyl­amino)ethyl­idene]oxonium cations and methane­sulfonate anions are linked into chains along the a axis via O—H⋯O and N—H⋯O hydrogen bonds. All non-H atoms of the acetamido group are essentially planar, with a maximum deviation of 0.0085 (12) Å. In comparison with related structures, the carbonyl C=O bond is slightly elongated [1.249 (2) Å], whereas the amide C—N bond is shortened [1.292 (2) Å]. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969600/ /pubmed/21583164 http://dx.doi.org/10.1107/S1600536809017632 Text en © Vícha et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vícha, Robert
Nečas, Marek
Kozubková, Zuzana
Potáček, Milan
[1-(1-Adamantylamino)ethyl­idene]oxonium methane­sulfonate
title [1-(1-Adamantylamino)ethyl­idene]oxonium methane­sulfonate
title_full [1-(1-Adamantylamino)ethyl­idene]oxonium methane­sulfonate
title_fullStr [1-(1-Adamantylamino)ethyl­idene]oxonium methane­sulfonate
title_full_unstemmed [1-(1-Adamantylamino)ethyl­idene]oxonium methane­sulfonate
title_short [1-(1-Adamantylamino)ethyl­idene]oxonium methane­sulfonate
title_sort [1-(1-adamantylamino)ethyl­idene]oxonium methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969600/
https://www.ncbi.nlm.nih.gov/pubmed/21583164
http://dx.doi.org/10.1107/S1600536809017632
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AT kozubkovazuzana 11adamantylaminoethylideneoxoniummethanesulfonate
AT potacekmilan 11adamantylaminoethylideneoxoniummethanesulfonate

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