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5-[(3,4-Dimethoxybenzyl)aminomethylene]-2,2-dimethyl-1,3-dioxane-4,6-dione
The title compound, C(15)H(17)NO(6), is approximately planar, with dihedral angles of 3.11 (4) and 2.12 (4)° between the connecting aminomethylene unit and the planar part of the dioxane ring, and between the dimethoxybenzyl ring and the aminomethylene group, respectively. The dioxane ring exhi...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969602/ https://www.ncbi.nlm.nih.gov/pubmed/21583157 http://dx.doi.org/10.1107/S1600536809017413 |
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author | Li, Rui Shi, Jian-You Ding, Zhen-Yu Wei, Yu-Quan Ding, Jian |
author_facet | Li, Rui Shi, Jian-You Ding, Zhen-Yu Wei, Yu-Quan Ding, Jian |
author_sort | Li, Rui |
collection | PubMed |
description | The title compound, C(15)H(17)NO(6), is approximately planar, with dihedral angles of 3.11 (4) and 2.12 (4)° between the connecting aminomethylene unit and the planar part of the dioxane ring, and between the dimethoxybenzyl ring and the aminomethylene group, respectively. The dioxane ring exhibits a half-boat conformation, in which the C atom between the dioxane O atoms is 0.5471 (8) Å out of the plane. The molecule has an intramolecular N—H⋯O hydrogen bond which may stabilize the planar conformation. In the crystal, weak intermolecular C—H⋯O hydrogen-bonding contacts, result in the formation of sheets parallel to the ab plane. |
format | Text |
id | pubmed-2969602 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29696022010-12-30 5-[(3,4-Dimethoxybenzyl)aminomethylene]-2,2-dimethyl-1,3-dioxane-4,6-dione Li, Rui Shi, Jian-You Ding, Zhen-Yu Wei, Yu-Quan Ding, Jian Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(17)NO(6), is approximately planar, with dihedral angles of 3.11 (4) and 2.12 (4)° between the connecting aminomethylene unit and the planar part of the dioxane ring, and between the dimethoxybenzyl ring and the aminomethylene group, respectively. The dioxane ring exhibits a half-boat conformation, in which the C atom between the dioxane O atoms is 0.5471 (8) Å out of the plane. The molecule has an intramolecular N—H⋯O hydrogen bond which may stabilize the planar conformation. In the crystal, weak intermolecular C—H⋯O hydrogen-bonding contacts, result in the formation of sheets parallel to the ab plane. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969602/ /pubmed/21583157 http://dx.doi.org/10.1107/S1600536809017413 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Rui Shi, Jian-You Ding, Zhen-Yu Wei, Yu-Quan Ding, Jian 5-[(3,4-Dimethoxybenzyl)aminomethylene]-2,2-dimethyl-1,3-dioxane-4,6-dione |
title | 5-[(3,4-Dimethoxybenzyl)aminomethylene]-2,2-dimethyl-1,3-dioxane-4,6-dione |
title_full | 5-[(3,4-Dimethoxybenzyl)aminomethylene]-2,2-dimethyl-1,3-dioxane-4,6-dione |
title_fullStr | 5-[(3,4-Dimethoxybenzyl)aminomethylene]-2,2-dimethyl-1,3-dioxane-4,6-dione |
title_full_unstemmed | 5-[(3,4-Dimethoxybenzyl)aminomethylene]-2,2-dimethyl-1,3-dioxane-4,6-dione |
title_short | 5-[(3,4-Dimethoxybenzyl)aminomethylene]-2,2-dimethyl-1,3-dioxane-4,6-dione |
title_sort | 5-[(3,4-dimethoxybenzyl)aminomethylene]-2,2-dimethyl-1,3-dioxane-4,6-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969602/ https://www.ncbi.nlm.nih.gov/pubmed/21583157 http://dx.doi.org/10.1107/S1600536809017413 |
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