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5-[(3,4-Dimethoxy­benzyl)­aminomethyl­ene]-2,2-dimethyl-1,3-dioxane-4,6-dione

The title compound, C(15)H(17)NO(6), is approximately planar, with dihedral angles of 3.11 (4) and 2.12 (4)° between the connecting amino­methyl­ene unit and the planar part of the dioxane ring, and between the dimethoxy­benzyl ring and the amino­methyl­ene group, respectively. The dioxane ring exhi...

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Detalles Bibliográficos
Autores principales: Li, Rui, Shi, Jian-You, Ding, Zhen-Yu, Wei, Yu-Quan, Ding, Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969602/
https://www.ncbi.nlm.nih.gov/pubmed/21583157
http://dx.doi.org/10.1107/S1600536809017413
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author Li, Rui
Shi, Jian-You
Ding, Zhen-Yu
Wei, Yu-Quan
Ding, Jian
author_facet Li, Rui
Shi, Jian-You
Ding, Zhen-Yu
Wei, Yu-Quan
Ding, Jian
author_sort Li, Rui
collection PubMed
description The title compound, C(15)H(17)NO(6), is approximately planar, with dihedral angles of 3.11 (4) and 2.12 (4)° between the connecting amino­methyl­ene unit and the planar part of the dioxane ring, and between the dimethoxy­benzyl ring and the amino­methyl­ene group, respectively. The dioxane ring exhibits a half-boat conformation, in which the C atom between the dioxane O atoms is 0.5471 (8) Å out of the plane. The mol­ecule has an intra­molecular N—H⋯O hydrogen bond which may stabilize the planar conformation. In the crystal, weak inter­molecular C—H⋯O hydrogen-bonding contacts, result in the formation of sheets parallel to the ab plane.
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spelling pubmed-29696022010-12-30 5-[(3,4-Dimethoxy­benzyl)­aminomethyl­ene]-2,2-dimethyl-1,3-dioxane-4,6-dione Li, Rui Shi, Jian-You Ding, Zhen-Yu Wei, Yu-Quan Ding, Jian Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(17)NO(6), is approximately planar, with dihedral angles of 3.11 (4) and 2.12 (4)° between the connecting amino­methyl­ene unit and the planar part of the dioxane ring, and between the dimethoxy­benzyl ring and the amino­methyl­ene group, respectively. The dioxane ring exhibits a half-boat conformation, in which the C atom between the dioxane O atoms is 0.5471 (8) Å out of the plane. The mol­ecule has an intra­molecular N—H⋯O hydrogen bond which may stabilize the planar conformation. In the crystal, weak inter­molecular C—H⋯O hydrogen-bonding contacts, result in the formation of sheets parallel to the ab plane. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969602/ /pubmed/21583157 http://dx.doi.org/10.1107/S1600536809017413 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Rui
Shi, Jian-You
Ding, Zhen-Yu
Wei, Yu-Quan
Ding, Jian
5-[(3,4-Dimethoxy­benzyl)­aminomethyl­ene]-2,2-dimethyl-1,3-dioxane-4,6-dione
title 5-[(3,4-Dimethoxy­benzyl)­aminomethyl­ene]-2,2-dimethyl-1,3-dioxane-4,6-dione
title_full 5-[(3,4-Dimethoxy­benzyl)­aminomethyl­ene]-2,2-dimethyl-1,3-dioxane-4,6-dione
title_fullStr 5-[(3,4-Dimethoxy­benzyl)­aminomethyl­ene]-2,2-dimethyl-1,3-dioxane-4,6-dione
title_full_unstemmed 5-[(3,4-Dimethoxy­benzyl)­aminomethyl­ene]-2,2-dimethyl-1,3-dioxane-4,6-dione
title_short 5-[(3,4-Dimethoxy­benzyl)­aminomethyl­ene]-2,2-dimethyl-1,3-dioxane-4,6-dione
title_sort 5-[(3,4-dimethoxy­benzyl)­aminomethyl­ene]-2,2-dimethyl-1,3-dioxane-4,6-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969602/
https://www.ncbi.nlm.nih.gov/pubmed/21583157
http://dx.doi.org/10.1107/S1600536809017413
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