Bis(2,2′-bipyridyl-κ(2) N,N′)(nitrato-κ(2) O,O′)(trifluoro­acetato-κO)cadmium(II)

In the title complex, [Cd(C(2)F(3)O(2))(NO(3))(C(10)H(8)N(2))(2)], the Cd(II) ion is hepta­coordinated by two chelating 2,2′-bipyridyl ligands [Cd⋯N 2.370 (6)–2.416 (6) Å], one carboxyl­ate O atom [Cd⋯O 2.290 (6) Å] from the trifluoro­acetate ligand and two O atoms [Cd⋯O 2.386 (6), 2.633 (6) Å] from...

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Detalles Bibliográficos
Autores principales: Duan, Wenzeng, Sun, Junshan, Ma, Yudao, Wu, Rentao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969603/
https://www.ncbi.nlm.nih.gov/pubmed/21583003
http://dx.doi.org/10.1107/S1600536809016717
Descripción
Sumario:In the title complex, [Cd(C(2)F(3)O(2))(NO(3))(C(10)H(8)N(2))(2)], the Cd(II) ion is hepta­coordinated by two chelating 2,2′-bipyridyl ligands [Cd⋯N 2.370 (6)–2.416 (6) Å], one carboxyl­ate O atom [Cd⋯O 2.290 (6) Å] from the trifluoro­acetate ligand and two O atoms [Cd⋯O 2.386 (6), 2.633 (6) Å] from a chelating nitrate anion. The trifluoro­methyl fragment is rotationally disordered between two orientations in a 0.640 (7):0.360 (7) ratio. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds contribute to the crystal packing stability.

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