Bis(2,2′-bipyridyl-κ(2) N,N′)(nitrato-κ(2) O,O′)(trifluoro­acetato-κO)cadmium(II)

In the title complex, [Cd(C(2)F(3)O(2))(NO(3))(C(10)H(8)N(2))(2)], the Cd(II) ion is hepta­coordinated by two chelating 2,2′-bipyridyl ligands [Cd⋯N 2.370 (6)–2.416 (6) Å], one carboxyl­ate O atom [Cd⋯O 2.290 (6) Å] from the trifluoro­acetate ligand and two O atoms [Cd⋯O 2.386 (6), 2.633 (6) Å] from...

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Detalles Bibliográficos
Autores principales: Duan, Wenzeng, Sun, Junshan, Ma, Yudao, Wu, Rentao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969603/
https://www.ncbi.nlm.nih.gov/pubmed/21583003
http://dx.doi.org/10.1107/S1600536809016717
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author Duan, Wenzeng
Sun, Junshan
Ma, Yudao
Wu, Rentao
author_facet Duan, Wenzeng
Sun, Junshan
Ma, Yudao
Wu, Rentao
author_sort Duan, Wenzeng
collection PubMed
description In the title complex, [Cd(C(2)F(3)O(2))(NO(3))(C(10)H(8)N(2))(2)], the Cd(II) ion is hepta­coordinated by two chelating 2,2′-bipyridyl ligands [Cd⋯N 2.370 (6)–2.416 (6) Å], one carboxyl­ate O atom [Cd⋯O 2.290 (6) Å] from the trifluoro­acetate ligand and two O atoms [Cd⋯O 2.386 (6), 2.633 (6) Å] from a chelating nitrate anion. The trifluoro­methyl fragment is rotationally disordered between two orientations in a 0.640 (7):0.360 (7) ratio. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds contribute to the crystal packing stability.
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spelling pubmed-29696032010-12-30 Bis(2,2′-bipyridyl-κ(2) N,N′)(nitrato-κ(2) O,O′)(trifluoro­acetato-κO)cadmium(II) Duan, Wenzeng Sun, Junshan Ma, Yudao Wu, Rentao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(2)F(3)O(2))(NO(3))(C(10)H(8)N(2))(2)], the Cd(II) ion is hepta­coordinated by two chelating 2,2′-bipyridyl ligands [Cd⋯N 2.370 (6)–2.416 (6) Å], one carboxyl­ate O atom [Cd⋯O 2.290 (6) Å] from the trifluoro­acetate ligand and two O atoms [Cd⋯O 2.386 (6), 2.633 (6) Å] from a chelating nitrate anion. The trifluoro­methyl fragment is rotationally disordered between two orientations in a 0.640 (7):0.360 (7) ratio. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds contribute to the crystal packing stability. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969603/ /pubmed/21583003 http://dx.doi.org/10.1107/S1600536809016717 Text en © Duan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Duan, Wenzeng
Sun, Junshan
Ma, Yudao
Wu, Rentao
Bis(2,2′-bipyridyl-κ(2) N,N′)(nitrato-κ(2) O,O′)(trifluoro­acetato-κO)cadmium(II)
title Bis(2,2′-bipyridyl-κ(2) N,N′)(nitrato-κ(2) O,O′)(trifluoro­acetato-κO)cadmium(II)
title_full Bis(2,2′-bipyridyl-κ(2) N,N′)(nitrato-κ(2) O,O′)(trifluoro­acetato-κO)cadmium(II)
title_fullStr Bis(2,2′-bipyridyl-κ(2) N,N′)(nitrato-κ(2) O,O′)(trifluoro­acetato-κO)cadmium(II)
title_full_unstemmed Bis(2,2′-bipyridyl-κ(2) N,N′)(nitrato-κ(2) O,O′)(trifluoro­acetato-κO)cadmium(II)
title_short Bis(2,2′-bipyridyl-κ(2) N,N′)(nitrato-κ(2) O,O′)(trifluoro­acetato-κO)cadmium(II)
title_sort bis(2,2′-bipyridyl-κ(2) n,n′)(nitrato-κ(2) o,o′)(trifluoro­acetato-κo)cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969603/
https://www.ncbi.nlm.nih.gov/pubmed/21583003
http://dx.doi.org/10.1107/S1600536809016717
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AT mayudao bis22bipyridylk2nnnitratok2ootrifluoroacetatokocadmiumii
AT wurentao bis22bipyridylk2nnnitratok2ootrifluoroacetatokocadmiumii

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