3-(9-Anthrylmethyl)-1-benzylperimi­dinium hexa­fluoro­phosphate

In the title compound, C(33)H(25)N(2) (+)·PF(6) (−), the naphthalene ring system is twisted with respect to the anthracene and benzene rings, making dihedral angles of 72.40 (3) and 71.39 (4)°, respectively. The crystal structure is stabilized by intermolecular C—H⋯F hydrogen bonding. Four F atoms o...

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Detalles Bibliográficos
Autores principales: Wang, Gui-Yu, Zhang, Shi-Lu, Qin, Da-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969606/
https://www.ncbi.nlm.nih.gov/pubmed/21583136
http://dx.doi.org/10.1107/S1600536809017140
Descripción
Sumario:In the title compound, C(33)H(25)N(2) (+)·PF(6) (−), the naphthalene ring system is twisted with respect to the anthracene and benzene rings, making dihedral angles of 72.40 (3) and 71.39 (4)°, respectively. The crystal structure is stabilized by intermolecular C—H⋯F hydrogen bonding. Four F atoms of the hexa­fluoro­phosphate anion are disordered over two sets of sites in a 0.645 (4):0.355 (4) ratio.

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