3-(9-Anthrylmethyl)-1-benzylperimi­dinium hexa­fluoro­phosphate

In the title compound, C(33)H(25)N(2) (+)·PF(6) (−), the naphthalene ring system is twisted with respect to the anthracene and benzene rings, making dihedral angles of 72.40 (3) and 71.39 (4)°, respectively. The crystal structure is stabilized by intermolecular C—H⋯F hydrogen bonding. Four F atoms o...

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Detalles Bibliográficos
Autores principales: Wang, Gui-Yu, Zhang, Shi-Lu, Qin, Da-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969606/
https://www.ncbi.nlm.nih.gov/pubmed/21583136
http://dx.doi.org/10.1107/S1600536809017140
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author Wang, Gui-Yu
Zhang, Shi-Lu
Qin, Da-Bin
author_facet Wang, Gui-Yu
Zhang, Shi-Lu
Qin, Da-Bin
author_sort Wang, Gui-Yu
collection PubMed
description In the title compound, C(33)H(25)N(2) (+)·PF(6) (−), the naphthalene ring system is twisted with respect to the anthracene and benzene rings, making dihedral angles of 72.40 (3) and 71.39 (4)°, respectively. The crystal structure is stabilized by intermolecular C—H⋯F hydrogen bonding. Four F atoms of the hexa­fluoro­phosphate anion are disordered over two sets of sites in a 0.645 (4):0.355 (4) ratio.
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spelling pubmed-29696062010-12-30 3-(9-Anthrylmethyl)-1-benzylperimi­dinium hexa­fluoro­phosphate Wang, Gui-Yu Zhang, Shi-Lu Qin, Da-Bin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(33)H(25)N(2) (+)·PF(6) (−), the naphthalene ring system is twisted with respect to the anthracene and benzene rings, making dihedral angles of 72.40 (3) and 71.39 (4)°, respectively. The crystal structure is stabilized by intermolecular C—H⋯F hydrogen bonding. Four F atoms of the hexa­fluoro­phosphate anion are disordered over two sets of sites in a 0.645 (4):0.355 (4) ratio. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969606/ /pubmed/21583136 http://dx.doi.org/10.1107/S1600536809017140 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Gui-Yu
Zhang, Shi-Lu
Qin, Da-Bin
3-(9-Anthrylmethyl)-1-benzylperimi­dinium hexa­fluoro­phosphate
title 3-(9-Anthrylmethyl)-1-benzylperimi­dinium hexa­fluoro­phosphate
title_full 3-(9-Anthrylmethyl)-1-benzylperimi­dinium hexa­fluoro­phosphate
title_fullStr 3-(9-Anthrylmethyl)-1-benzylperimi­dinium hexa­fluoro­phosphate
title_full_unstemmed 3-(9-Anthrylmethyl)-1-benzylperimi­dinium hexa­fluoro­phosphate
title_short 3-(9-Anthrylmethyl)-1-benzylperimi­dinium hexa­fluoro­phosphate
title_sort 3-(9-anthrylmethyl)-1-benzylperimi­dinium hexa­fluoro­phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969606/
https://www.ncbi.nlm.nih.gov/pubmed/21583136
http://dx.doi.org/10.1107/S1600536809017140
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AT qindabin 39anthrylmethyl1benzylperimidiniumhexafluorophosphate

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