N-[4-Acetyl-5-(2-methylprop-1-enyl)-5-(2-p-tolyl­prop­yl)-4,5-dihydro-1,3,4-thia­diazol-2-yl]acetamide

The title heterocyclic compound, C(20)H(27)N(3)O(2)S, was synthesized from 2-(4-methyl­cyclo­hex-3-en­yl)-6-methyl­hepta-2,5-dien-4-one, which was isolated from the essential oil Cedrus atlantica. The thia­diazole ring is essentially planar [maximum deviation 0.006 (2) Å] and it forms a dihedral ang...

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Detalles Bibliográficos
Autores principales: Mazoir, Noureddine, El Ammari, Lahcen, Bouhmaida, Nouzha, Dahaoui, Slimane, Benharref, Ahmed, Berraho, Moha
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969617/
https://www.ncbi.nlm.nih.gov/pubmed/21583133
http://dx.doi.org/10.1107/S1600536809017127
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author Mazoir, Noureddine
El Ammari, Lahcen
Bouhmaida, Nouzha
Dahaoui, Slimane
Benharref, Ahmed
Berraho, Moha
author_facet Mazoir, Noureddine
El Ammari, Lahcen
Bouhmaida, Nouzha
Dahaoui, Slimane
Benharref, Ahmed
Berraho, Moha
author_sort Mazoir, Noureddine
collection PubMed
description The title heterocyclic compound, C(20)H(27)N(3)O(2)S, was synthesized from 2-(4-methyl­cyclo­hex-3-en­yl)-6-methyl­hepta-2,5-dien-4-one, which was isolated from the essential oil Cedrus atlantica. The thia­diazole ring is essentially planar [maximum deviation 0.006 (2) Å] and it forms a dihedral angle of 18.08 (9)° with the benzene ring. The dihedral angle between the thia­diazole ring and the acetamide plane is 7.62 (10)°. In the crystal, mol­ecules are linked into chains running along the c axis by inter­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-29696172010-12-30 N-[4-Acetyl-5-(2-methylprop-1-enyl)-5-(2-p-tolyl­prop­yl)-4,5-dihydro-1,3,4-thia­diazol-2-yl]acetamide Mazoir, Noureddine El Ammari, Lahcen Bouhmaida, Nouzha Dahaoui, Slimane Benharref, Ahmed Berraho, Moha Acta Crystallogr Sect E Struct Rep Online Organic Papers The title heterocyclic compound, C(20)H(27)N(3)O(2)S, was synthesized from 2-(4-methyl­cyclo­hex-3-en­yl)-6-methyl­hepta-2,5-dien-4-one, which was isolated from the essential oil Cedrus atlantica. The thia­diazole ring is essentially planar [maximum deviation 0.006 (2) Å] and it forms a dihedral angle of 18.08 (9)° with the benzene ring. The dihedral angle between the thia­diazole ring and the acetamide plane is 7.62 (10)°. In the crystal, mol­ecules are linked into chains running along the c axis by inter­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969617/ /pubmed/21583133 http://dx.doi.org/10.1107/S1600536809017127 Text en © Mazoir et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mazoir, Noureddine
El Ammari, Lahcen
Bouhmaida, Nouzha
Dahaoui, Slimane
Benharref, Ahmed
Berraho, Moha
N-[4-Acetyl-5-(2-methylprop-1-enyl)-5-(2-p-tolyl­prop­yl)-4,5-dihydro-1,3,4-thia­diazol-2-yl]acetamide
title N-[4-Acetyl-5-(2-methylprop-1-enyl)-5-(2-p-tolyl­prop­yl)-4,5-dihydro-1,3,4-thia­diazol-2-yl]acetamide
title_full N-[4-Acetyl-5-(2-methylprop-1-enyl)-5-(2-p-tolyl­prop­yl)-4,5-dihydro-1,3,4-thia­diazol-2-yl]acetamide
title_fullStr N-[4-Acetyl-5-(2-methylprop-1-enyl)-5-(2-p-tolyl­prop­yl)-4,5-dihydro-1,3,4-thia­diazol-2-yl]acetamide
title_full_unstemmed N-[4-Acetyl-5-(2-methylprop-1-enyl)-5-(2-p-tolyl­prop­yl)-4,5-dihydro-1,3,4-thia­diazol-2-yl]acetamide
title_short N-[4-Acetyl-5-(2-methylprop-1-enyl)-5-(2-p-tolyl­prop­yl)-4,5-dihydro-1,3,4-thia­diazol-2-yl]acetamide
title_sort n-[4-acetyl-5-(2-methylprop-1-enyl)-5-(2-p-tolyl­prop­yl)-4,5-dihydro-1,3,4-thia­diazol-2-yl]acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969617/
https://www.ncbi.nlm.nih.gov/pubmed/21583133
http://dx.doi.org/10.1107/S1600536809017127
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