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N,N′-Bis[(E)-(6-methyl-2-pyridyl)methylene]hexane-1,6-diamine
The title compound, C(20)H(26)N(4), is composed of two (6-methyl-2-pyridyl)methylene units linked by a 1,6-diamine hexane chain. The molecule has C(i) symmetry with the inversion center situated at the mid-point of the central C—C bond. The alkyl chain has an all-trans conformation, with all the n...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969618/ https://www.ncbi.nlm.nih.gov/pubmed/21583120 http://dx.doi.org/10.1107/S1600536809016730 |
Sumario: | The title compound, C(20)H(26)N(4), is composed of two (6-methyl-2-pyridyl)methylene units linked by a 1,6-diamine hexane chain. The molecule has C(i) symmetry with the inversion center situated at the mid-point of the central C—C bond. The alkyl chain has an all-trans conformation, with all the non-H atoms sharing the same plane [maximum deviation 0.004 (3) Å]. The pyridylmethylene groups are also planar [maximum deviation 0.009 (3) Å], making an angle of 53.78 (19)° with the hexane chain plane. In the crystal, the molecules assemble in layers, stacking along the a axis. The stacks are hold together by attractive interactions between π electron systems. |
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