N,N′-Bis­[(E)-(6-methyl-2-pyridyl)­methyl­ene]hexane-1,6-diamine

The title compound, C(20)H(26)N(4), is composed of two (6-methyl-2-pyridyl)methyl­ene units linked by a 1,6-diamine hexane chain. The mol­ecule has C(i) symmetry with the inversion center situated at the mid-point of the central C—C bond. The alkyl chain has an all-trans conformation, with all the n...

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Detalles Bibliográficos
Autores principales: Ramos Silva, Manuela, Silva, Joana A., Matos Beja, Ana, Sobral, Abilio J. F.N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969618/
https://www.ncbi.nlm.nih.gov/pubmed/21583120
http://dx.doi.org/10.1107/S1600536809016730
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author Ramos Silva, Manuela
Silva, Joana A.
Matos Beja, Ana
Sobral, Abilio J. F.N.
author_facet Ramos Silva, Manuela
Silva, Joana A.
Matos Beja, Ana
Sobral, Abilio J. F.N.
author_sort Ramos Silva, Manuela
collection PubMed
description The title compound, C(20)H(26)N(4), is composed of two (6-methyl-2-pyridyl)methyl­ene units linked by a 1,6-diamine hexane chain. The mol­ecule has C(i) symmetry with the inversion center situated at the mid-point of the central C—C bond. The alkyl chain has an all-trans conformation, with all the non-H atoms sharing the same plane [maximum deviation 0.004 (3) Å]. The pyridylmethyl­ene groups are also planar [maximum deviation 0.009 (3) Å], making an angle of 53.78 (19)° with the hexane chain plane. In the crystal, the mol­ecules assemble in layers, stacking along the a axis. The stacks are hold together by attractive interactions between π electron systems.
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spelling pubmed-29696182010-12-30 N,N′-Bis­[(E)-(6-methyl-2-pyridyl)­methyl­ene]hexane-1,6-diamine Ramos Silva, Manuela Silva, Joana A. Matos Beja, Ana Sobral, Abilio J. F.N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(26)N(4), is composed of two (6-methyl-2-pyridyl)methyl­ene units linked by a 1,6-diamine hexane chain. The mol­ecule has C(i) symmetry with the inversion center situated at the mid-point of the central C—C bond. The alkyl chain has an all-trans conformation, with all the non-H atoms sharing the same plane [maximum deviation 0.004 (3) Å]. The pyridylmethyl­ene groups are also planar [maximum deviation 0.009 (3) Å], making an angle of 53.78 (19)° with the hexane chain plane. In the crystal, the mol­ecules assemble in layers, stacking along the a axis. The stacks are hold together by attractive interactions between π electron systems. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969618/ /pubmed/21583120 http://dx.doi.org/10.1107/S1600536809016730 Text en © Ramos Silva et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ramos Silva, Manuela
Silva, Joana A.
Matos Beja, Ana
Sobral, Abilio J. F.N.
N,N′-Bis­[(E)-(6-methyl-2-pyridyl)­methyl­ene]hexane-1,6-diamine
title N,N′-Bis­[(E)-(6-methyl-2-pyridyl)­methyl­ene]hexane-1,6-diamine
title_full N,N′-Bis­[(E)-(6-methyl-2-pyridyl)­methyl­ene]hexane-1,6-diamine
title_fullStr N,N′-Bis­[(E)-(6-methyl-2-pyridyl)­methyl­ene]hexane-1,6-diamine
title_full_unstemmed N,N′-Bis­[(E)-(6-methyl-2-pyridyl)­methyl­ene]hexane-1,6-diamine
title_short N,N′-Bis­[(E)-(6-methyl-2-pyridyl)­methyl­ene]hexane-1,6-diamine
title_sort n,n′-bis­[(e)-(6-methyl-2-pyridyl)­methyl­ene]hexane-1,6-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969618/
https://www.ncbi.nlm.nih.gov/pubmed/21583120
http://dx.doi.org/10.1107/S1600536809016730
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