Redetermination of bis­(O,O′-diethyl dithio­phosphato-κ(2) S,S′)nickel(II)

The centrosymmetric title complex, [Ni{S(2)P(OC(2)H(5))(2)}(2)], has been redetermined using area-detector data. The central Ni(S(2)P)(2) core is essentially planar and confirms the early results of McConnell & Kastalsky [Acta Cryst. (1967), 22, 853–859] based on multiple film technique data. In...

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Detalles Bibliográficos
Autores principales: Paliwoda, Damian, Chojnacki, Jarosław, Mietlarek-Kropidłowska, Anna, Becker, Barbara
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969620/
https://www.ncbi.nlm.nih.gov/pubmed/21583024
http://dx.doi.org/10.1107/S160053680901767X
Descripción
Sumario:The centrosymmetric title complex, [Ni{S(2)P(OC(2)H(5))(2)}(2)], has been redetermined using area-detector data. The central Ni(S(2)P)(2) core is essentially planar and confirms the early results of McConnell & Kastalsky [Acta Cryst. (1967), 22, 853–859] based on multiple film technique data. In the title structure, the standard uncertainty values are approximately seven times lower and all H-atom positions are calculated. A pair of short symmetry-related H⋯H contacts with distances of 2.33 Å is observed in the crystal structure.

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