Redetermination of bis­(O,O′-diethyl dithio­phosphato-κ(2) S,S′)nickel(II)

The centrosymmetric title complex, [Ni{S(2)P(OC(2)H(5))(2)}(2)], has been redetermined using area-detector data. The central Ni(S(2)P)(2) core is essentially planar and confirms the early results of McConnell & Kastalsky [Acta Cryst. (1967), 22, 853–859] based on multiple film technique data. In...

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Autores principales: Paliwoda, Damian, Chojnacki, Jarosław, Mietlarek-Kropidłowska, Anna, Becker, Barbara
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969620/
https://www.ncbi.nlm.nih.gov/pubmed/21583024
http://dx.doi.org/10.1107/S160053680901767X
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author Paliwoda, Damian
Chojnacki, Jarosław
Mietlarek-Kropidłowska, Anna
Becker, Barbara
author_facet Paliwoda, Damian
Chojnacki, Jarosław
Mietlarek-Kropidłowska, Anna
Becker, Barbara
author_sort Paliwoda, Damian
collection PubMed
description The centrosymmetric title complex, [Ni{S(2)P(OC(2)H(5))(2)}(2)], has been redetermined using area-detector data. The central Ni(S(2)P)(2) core is essentially planar and confirms the early results of McConnell & Kastalsky [Acta Cryst. (1967), 22, 853–859] based on multiple film technique data. In the title structure, the standard uncertainty values are approximately seven times lower and all H-atom positions are calculated. A pair of short symmetry-related H⋯H contacts with distances of 2.33 Å is observed in the crystal structure.
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spelling pubmed-29696202010-12-30 Redetermination of bis­(O,O′-diethyl dithio­phosphato-κ(2) S,S′)nickel(II) Paliwoda, Damian Chojnacki, Jarosław Mietlarek-Kropidłowska, Anna Becker, Barbara Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The centrosymmetric title complex, [Ni{S(2)P(OC(2)H(5))(2)}(2)], has been redetermined using area-detector data. The central Ni(S(2)P)(2) core is essentially planar and confirms the early results of McConnell & Kastalsky [Acta Cryst. (1967), 22, 853–859] based on multiple film technique data. In the title structure, the standard uncertainty values are approximately seven times lower and all H-atom positions are calculated. A pair of short symmetry-related H⋯H contacts with distances of 2.33 Å is observed in the crystal structure. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969620/ /pubmed/21583024 http://dx.doi.org/10.1107/S160053680901767X Text en © Paliwoda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Paliwoda, Damian
Chojnacki, Jarosław
Mietlarek-Kropidłowska, Anna
Becker, Barbara
Redetermination of bis­(O,O′-diethyl dithio­phosphato-κ(2) S,S′)nickel(II)
title Redetermination of bis­(O,O′-diethyl dithio­phosphato-κ(2) S,S′)nickel(II)
title_full Redetermination of bis­(O,O′-diethyl dithio­phosphato-κ(2) S,S′)nickel(II)
title_fullStr Redetermination of bis­(O,O′-diethyl dithio­phosphato-κ(2) S,S′)nickel(II)
title_full_unstemmed Redetermination of bis­(O,O′-diethyl dithio­phosphato-κ(2) S,S′)nickel(II)
title_short Redetermination of bis­(O,O′-diethyl dithio­phosphato-κ(2) S,S′)nickel(II)
title_sort redetermination of bis­(o,o′-diethyl dithio­phosphato-κ(2) s,s′)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969620/
https://www.ncbi.nlm.nih.gov/pubmed/21583024
http://dx.doi.org/10.1107/S160053680901767X
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