(E)-2-[(3,5-Di-tert-butyl-2-hydroxy­benzyl­idene)amino]benzonitrile

The asymmetric unit of the title compound, C(22)H(26)N(2)O, contains three crystallographically independent mol­ecules, in which the aromatic rings are oriented at dihedral angles of 21.74 (5), 27.59 (5) and 27.87 (5)°. Intra­molecular O—H⋯N hydrogen bonds result in the formation of planar six-membe...

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Detalles Bibliográficos
Autores principales: Zhou, Jian-Cheng, Li, Nai-Xu, Zhang, Chuan-Ming, Zhang, Zheng-Yun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969623/
https://www.ncbi.nlm.nih.gov/pubmed/21583259
http://dx.doi.org/10.1107/S1600536809019527
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author Zhou, Jian-Cheng
Li, Nai-Xu
Zhang, Chuan-Ming
Zhang, Zheng-Yun
author_facet Zhou, Jian-Cheng
Li, Nai-Xu
Zhang, Chuan-Ming
Zhang, Zheng-Yun
author_sort Zhou, Jian-Cheng
collection PubMed
description The asymmetric unit of the title compound, C(22)H(26)N(2)O, contains three crystallographically independent mol­ecules, in which the aromatic rings are oriented at dihedral angles of 21.74 (5), 27.59 (5) and 27.87 (5)°. Intra­molecular O—H⋯N hydrogen bonds result in the formation of planar six-membered rings, and these are nearly coplanar with the adjacent rings. In the crystal structure, π–π contacts between the benzene rings [centroid–centroid distances = 3.989 (2), 3.802 (1) and 3.882 (1) Å] may stabilize the structure.
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spelling pubmed-29696232010-12-30 (E)-2-[(3,5-Di-tert-butyl-2-hydroxy­benzyl­idene)amino]benzonitrile Zhou, Jian-Cheng Li, Nai-Xu Zhang, Chuan-Ming Zhang, Zheng-Yun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(22)H(26)N(2)O, contains three crystallographically independent mol­ecules, in which the aromatic rings are oriented at dihedral angles of 21.74 (5), 27.59 (5) and 27.87 (5)°. Intra­molecular O—H⋯N hydrogen bonds result in the formation of planar six-membered rings, and these are nearly coplanar with the adjacent rings. In the crystal structure, π–π contacts between the benzene rings [centroid–centroid distances = 3.989 (2), 3.802 (1) and 3.882 (1) Å] may stabilize the structure. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969623/ /pubmed/21583259 http://dx.doi.org/10.1107/S1600536809019527 Text en © Zhou et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhou, Jian-Cheng
Li, Nai-Xu
Zhang, Chuan-Ming
Zhang, Zheng-Yun
(E)-2-[(3,5-Di-tert-butyl-2-hydroxy­benzyl­idene)amino]benzonitrile
title (E)-2-[(3,5-Di-tert-butyl-2-hydroxy­benzyl­idene)amino]benzonitrile
title_full (E)-2-[(3,5-Di-tert-butyl-2-hydroxy­benzyl­idene)amino]benzonitrile
title_fullStr (E)-2-[(3,5-Di-tert-butyl-2-hydroxy­benzyl­idene)amino]benzonitrile
title_full_unstemmed (E)-2-[(3,5-Di-tert-butyl-2-hydroxy­benzyl­idene)amino]benzonitrile
title_short (E)-2-[(3,5-Di-tert-butyl-2-hydroxy­benzyl­idene)amino]benzonitrile
title_sort (e)-2-[(3,5-di-tert-butyl-2-hydroxy­benzyl­idene)amino]benzonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969623/
https://www.ncbi.nlm.nih.gov/pubmed/21583259
http://dx.doi.org/10.1107/S1600536809019527
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