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Hexaaquacadmium(II) dipicrate monohydrate
In the structure of the title compound, [Cd(H(2)O)(6)](C(6)H(2)N(3)O(7))(2)·H(2)O, the Cd(II) ion is located on an inversion center and is coordinated by six water molecules in an octahedral geometry. The picrate anions have no coordination interactions with the Cd(II) ion. The three nitro groups...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969625/ https://www.ncbi.nlm.nih.gov/pubmed/21582990 http://dx.doi.org/10.1107/S1600536809015049 |
| _version_ | 1782190207530958848 |
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| author | Natarajan, S. Moovendaran, K. Dhas, S. A. Martin Britto Suresh, J. Lakshman, P. L. Nilantha |
| author_facet | Natarajan, S. Moovendaran, K. Dhas, S. A. Martin Britto Suresh, J. Lakshman, P. L. Nilantha |
| author_sort | Natarajan, S. |
| collection | PubMed |
| description | In the structure of the title compound, [Cd(H(2)O)(6)](C(6)H(2)N(3)O(7))(2)·H(2)O, the Cd(II) ion is located on an inversion center and is coordinated by six water molecules in an octahedral geometry. The picrate anions have no coordination interactions with the Cd(II) ion. The three nitro groups are twisted away from the attached benzene ring, making dihedral angles of 17.89 (3), 27.94 (4) and 13.65 (3)°. There are numerous O—H⋯O hydrogen bonds in the crystal structure, involving coordinated and uncoordinated water molecules. |
| format | Text |
| id | pubmed-2969625 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29696252010-12-30 Hexaaquacadmium(II) dipicrate monohydrate Natarajan, S. Moovendaran, K. Dhas, S. A. Martin Britto Suresh, J. Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Cd(H(2)O)(6)](C(6)H(2)N(3)O(7))(2)·H(2)O, the Cd(II) ion is located on an inversion center and is coordinated by six water molecules in an octahedral geometry. The picrate anions have no coordination interactions with the Cd(II) ion. The three nitro groups are twisted away from the attached benzene ring, making dihedral angles of 17.89 (3), 27.94 (4) and 13.65 (3)°. There are numerous O—H⋯O hydrogen bonds in the crystal structure, involving coordinated and uncoordinated water molecules. International Union of Crystallography 2009-05-07 /pmc/articles/PMC2969625/ /pubmed/21582990 http://dx.doi.org/10.1107/S1600536809015049 Text en © Natarajan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Natarajan, S. Moovendaran, K. Dhas, S. A. Martin Britto Suresh, J. Lakshman, P. L. Nilantha Hexaaquacadmium(II) dipicrate monohydrate |
| title | Hexaaquacadmium(II) dipicrate monohydrate |
| title_full | Hexaaquacadmium(II) dipicrate monohydrate |
| title_fullStr | Hexaaquacadmium(II) dipicrate monohydrate |
| title_full_unstemmed | Hexaaquacadmium(II) dipicrate monohydrate |
| title_short | Hexaaquacadmium(II) dipicrate monohydrate |
| title_sort | hexaaquacadmium(ii) dipicrate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969625/ https://www.ncbi.nlm.nih.gov/pubmed/21582990 http://dx.doi.org/10.1107/S1600536809015049 |
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