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(E)-3-[4-(Hexyloxy)phenyl]-1-(2-hydroxyphenyl)prop-2-en-1-one
In the title compound, C(21)H(24)O(3), the conformation of the enone group is s–cis. The benzene rings are inclined at an angle of 7.9 (1)°. The alkoxy tail is planar, with a maximum deviation from the least-squares plane of 0.009 (2) Å, and adopts a trans conformation throughout. An intramolecula...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969631/ https://www.ncbi.nlm.nih.gov/pubmed/21583159 http://dx.doi.org/10.1107/S1600536809017577 |
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author | Ngaini, Zainab Fadzillah, Siti Muhaini Haris Hussain, Hasnain Razak, Ibrahim Abdul Fun, Hoong-Kun |
author_facet | Ngaini, Zainab Fadzillah, Siti Muhaini Haris Hussain, Hasnain Razak, Ibrahim Abdul Fun, Hoong-Kun |
author_sort | Ngaini, Zainab |
collection | PubMed |
description | In the title compound, C(21)H(24)O(3), the conformation of the enone group is s–cis. The benzene rings are inclined at an angle of 7.9 (1)°. The alkoxy tail is planar, with a maximum deviation from the least-squares plane of 0.009 (2) Å, and adopts a trans conformation throughout. An intramolecular O—H⋯O interaction between the keto and hydroxy groups forms S(6) ring motifs. In the crystal, molecules are arranged in a head-to-tail manner down the a axis and are subsequently stacked along the b axis, forming molecular sheets parallel to the ab plane. The crystal structure is further stabilized by weak C—H⋯π interactions and short C⋯O [3.376 (2) Å] contacts. |
format | Text |
id | pubmed-2969631 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29696312010-12-30 (E)-3-[4-(Hexyloxy)phenyl]-1-(2-hydroxyphenyl)prop-2-en-1-one Ngaini, Zainab Fadzillah, Siti Muhaini Haris Hussain, Hasnain Razak, Ibrahim Abdul Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(24)O(3), the conformation of the enone group is s–cis. The benzene rings are inclined at an angle of 7.9 (1)°. The alkoxy tail is planar, with a maximum deviation from the least-squares plane of 0.009 (2) Å, and adopts a trans conformation throughout. An intramolecular O—H⋯O interaction between the keto and hydroxy groups forms S(6) ring motifs. In the crystal, molecules are arranged in a head-to-tail manner down the a axis and are subsequently stacked along the b axis, forming molecular sheets parallel to the ab plane. The crystal structure is further stabilized by weak C—H⋯π interactions and short C⋯O [3.376 (2) Å] contacts. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969631/ /pubmed/21583159 http://dx.doi.org/10.1107/S1600536809017577 Text en © Ngaini et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ngaini, Zainab Fadzillah, Siti Muhaini Haris Hussain, Hasnain Razak, Ibrahim Abdul Fun, Hoong-Kun (E)-3-[4-(Hexyloxy)phenyl]-1-(2-hydroxyphenyl)prop-2-en-1-one |
title | (E)-3-[4-(Hexyloxy)phenyl]-1-(2-hydroxyphenyl)prop-2-en-1-one |
title_full | (E)-3-[4-(Hexyloxy)phenyl]-1-(2-hydroxyphenyl)prop-2-en-1-one |
title_fullStr | (E)-3-[4-(Hexyloxy)phenyl]-1-(2-hydroxyphenyl)prop-2-en-1-one |
title_full_unstemmed | (E)-3-[4-(Hexyloxy)phenyl]-1-(2-hydroxyphenyl)prop-2-en-1-one |
title_short | (E)-3-[4-(Hexyloxy)phenyl]-1-(2-hydroxyphenyl)prop-2-en-1-one |
title_sort | (e)-3-[4-(hexyloxy)phenyl]-1-(2-hydroxyphenyl)prop-2-en-1-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969631/ https://www.ncbi.nlm.nih.gov/pubmed/21583159 http://dx.doi.org/10.1107/S1600536809017577 |
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