(Z)-3-(9-Anthr­yl)-1-(4-bromo­phen­yl)-2-(4-nitro-1H-imidazol-1-yl)prop-2-en-1-one

In the title mol­ecule, C(26)H(16)BrN(3)O(3), the anthracene and benzene mean planes make dihedral angles of 63.79 (2) and 14.67 (2)°, respectively, with the plane of the imidazole ring. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds link mol­ecules to form centrosymmetric dimer...

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Detalles Bibliográficos
Autores principales: Lu, Yi-Hui, Wang, Guang-Zhou, Zhou, Cheng-He, Zhang, Yi-Yi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969633/
https://www.ncbi.nlm.nih.gov/pubmed/21583241
http://dx.doi.org/10.1107/S1600536809018352
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author Lu, Yi-Hui
Wang, Guang-Zhou
Zhou, Cheng-He
Zhang, Yi-Yi
author_facet Lu, Yi-Hui
Wang, Guang-Zhou
Zhou, Cheng-He
Zhang, Yi-Yi
author_sort Lu, Yi-Hui
collection PubMed
description In the title mol­ecule, C(26)H(16)BrN(3)O(3), the anthracene and benzene mean planes make dihedral angles of 63.79 (2) and 14.67 (2)°, respectively, with the plane of the imidazole ring. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds link mol­ecules to form centrosymmetric dimers. Weak π–π stacking inter­actions, with centroid–centroid distances of 3.779 (2) and 3.826 (2) Å, supply additional stabilization. The crystal packing also exhibits short inter­molecular contacts between the nitro groups and Br atoms [Br⋯O = 3.114 (2) Å].
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spelling pubmed-29696332010-12-30 (Z)-3-(9-Anthr­yl)-1-(4-bromo­phen­yl)-2-(4-nitro-1H-imidazol-1-yl)prop-2-en-1-one Lu, Yi-Hui Wang, Guang-Zhou Zhou, Cheng-He Zhang, Yi-Yi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(26)H(16)BrN(3)O(3), the anthracene and benzene mean planes make dihedral angles of 63.79 (2) and 14.67 (2)°, respectively, with the plane of the imidazole ring. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds link mol­ecules to form centrosymmetric dimers. Weak π–π stacking inter­actions, with centroid–centroid distances of 3.779 (2) and 3.826 (2) Å, supply additional stabilization. The crystal packing also exhibits short inter­molecular contacts between the nitro groups and Br atoms [Br⋯O = 3.114 (2) Å]. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969633/ /pubmed/21583241 http://dx.doi.org/10.1107/S1600536809018352 Text en © Lu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lu, Yi-Hui
Wang, Guang-Zhou
Zhou, Cheng-He
Zhang, Yi-Yi
(Z)-3-(9-Anthr­yl)-1-(4-bromo­phen­yl)-2-(4-nitro-1H-imidazol-1-yl)prop-2-en-1-one
title (Z)-3-(9-Anthr­yl)-1-(4-bromo­phen­yl)-2-(4-nitro-1H-imidazol-1-yl)prop-2-en-1-one
title_full (Z)-3-(9-Anthr­yl)-1-(4-bromo­phen­yl)-2-(4-nitro-1H-imidazol-1-yl)prop-2-en-1-one
title_fullStr (Z)-3-(9-Anthr­yl)-1-(4-bromo­phen­yl)-2-(4-nitro-1H-imidazol-1-yl)prop-2-en-1-one
title_full_unstemmed (Z)-3-(9-Anthr­yl)-1-(4-bromo­phen­yl)-2-(4-nitro-1H-imidazol-1-yl)prop-2-en-1-one
title_short (Z)-3-(9-Anthr­yl)-1-(4-bromo­phen­yl)-2-(4-nitro-1H-imidazol-1-yl)prop-2-en-1-one
title_sort (z)-3-(9-anthr­yl)-1-(4-bromo­phen­yl)-2-(4-nitro-1h-imidazol-1-yl)prop-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969633/
https://www.ncbi.nlm.nih.gov/pubmed/21583241
http://dx.doi.org/10.1107/S1600536809018352
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