2-(3-Pyridinio)benzimidazolium penta­chloridoanti­monate(III) monohydrate

In the title compound, (C(12)H(11)N(3))[SbCl(5)]·H(2)O, the Sb(III) centre is surrounded by five Cl atoms and displays a distorted square-pyramidal coordination geometry. The dihedral angle formed by the plane of the imidazole ring system with the pyridine ring is 4.380 (15)°. The crystal structure...

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Detalles Bibliográficos
Autores principales: Cui, Li-Jing, Xu, Hai-Jun, Pan, Ke-Ji
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969637/
https://www.ncbi.nlm.nih.gov/pubmed/21583035
http://dx.doi.org/10.1107/S1600536809018935
Descripción
Sumario:In the title compound, (C(12)H(11)N(3))[SbCl(5)]·H(2)O, the Sb(III) centre is surrounded by five Cl atoms and displays a distorted square-pyramidal coordination geometry. The dihedral angle formed by the plane of the imidazole ring system with the pyridine ring is 4.380 (15)°. The crystal structure is stabilized by N—H⋯Cl, O—H⋯Cl and N—H⋯O hydrogen bonds, forming a three-dimensional network.

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