2-(3-Pyridinio)benzimidazolium penta­chloridoanti­monate(III) monohydrate

In the title compound, (C(12)H(11)N(3))[SbCl(5)]·H(2)O, the Sb(III) centre is surrounded by five Cl atoms and displays a distorted square-pyramidal coordination geometry. The dihedral angle formed by the plane of the imidazole ring system with the pyridine ring is 4.380 (15)°. The crystal structure...

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Detalles Bibliográficos
Autores principales: Cui, Li-Jing, Xu, Hai-Jun, Pan, Ke-Ji
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969637/
https://www.ncbi.nlm.nih.gov/pubmed/21583035
http://dx.doi.org/10.1107/S1600536809018935
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author Cui, Li-Jing
Xu, Hai-Jun
Pan, Ke-Ji
author_facet Cui, Li-Jing
Xu, Hai-Jun
Pan, Ke-Ji
author_sort Cui, Li-Jing
collection PubMed
description In the title compound, (C(12)H(11)N(3))[SbCl(5)]·H(2)O, the Sb(III) centre is surrounded by five Cl atoms and displays a distorted square-pyramidal coordination geometry. The dihedral angle formed by the plane of the imidazole ring system with the pyridine ring is 4.380 (15)°. The crystal structure is stabilized by N—H⋯Cl, O—H⋯Cl and N—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-29696372010-12-30 2-(3-Pyridinio)benzimidazolium penta­chloridoanti­monate(III) monohydrate Cui, Li-Jing Xu, Hai-Jun Pan, Ke-Ji Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(12)H(11)N(3))[SbCl(5)]·H(2)O, the Sb(III) centre is surrounded by five Cl atoms and displays a distorted square-pyramidal coordination geometry. The dihedral angle formed by the plane of the imidazole ring system with the pyridine ring is 4.380 (15)°. The crystal structure is stabilized by N—H⋯Cl, O—H⋯Cl and N—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969637/ /pubmed/21583035 http://dx.doi.org/10.1107/S1600536809018935 Text en © Cui et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cui, Li-Jing
Xu, Hai-Jun
Pan, Ke-Ji
2-(3-Pyridinio)benzimidazolium penta­chloridoanti­monate(III) monohydrate
title 2-(3-Pyridinio)benzimidazolium penta­chloridoanti­monate(III) monohydrate
title_full 2-(3-Pyridinio)benzimidazolium penta­chloridoanti­monate(III) monohydrate
title_fullStr 2-(3-Pyridinio)benzimidazolium penta­chloridoanti­monate(III) monohydrate
title_full_unstemmed 2-(3-Pyridinio)benzimidazolium penta­chloridoanti­monate(III) monohydrate
title_short 2-(3-Pyridinio)benzimidazolium penta­chloridoanti­monate(III) monohydrate
title_sort 2-(3-pyridinio)benzimidazolium penta­chloridoanti­monate(iii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969637/
https://www.ncbi.nlm.nih.gov/pubmed/21583035
http://dx.doi.org/10.1107/S1600536809018935
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AT pankeji 23pyridiniobenzimidazoliumpentachloridoantimonateiiimonohydrate

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